Secondary deuterium isotope effects. Transition state in the reverse Diels-Alder reaction of 9,10-dihydro-9,10-ethanoanthrancene. Potentially general method for experimentally determining transition-state symmetry and distinguishing concerted from stepwise mechanisms

1972 ◽  
Vol 94 (4) ◽  
pp. 1168-1177 ◽  
Author(s):  
Mare Taagepera ◽  
Edward R. Thornton
Keyword(s):  
Transition State ◽  
Isotope Effects ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Deuterium Isotope Effects ◽  
General Method

Ab initio Cs transition state for the Diels-Alder reaction of acetylene and butadiene

1990 ◽  
Vol 55 (12) ◽  
pp. 3804-3807 ◽  
Author(s):  
James M. Coxon ◽  
Stephen T. Grice ◽  
Robert G. A. R. Maclagan ◽  
D. Quentin McDonald
Keyword(s):  
Transition State ◽  
Ab Initio ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

The synthesis of trisubstituted cyclopentadienes and their reactivity in the intramolecular Diels–Alder reaction

1984 ◽  
Vol 62 (1) ◽  
pp. 121-127 ◽  
Author(s):  
Sandra J. Alward ◽  
Alex G. Fallis
Keyword(s):  
Adverse Effect ◽  
Alder Reaction ◽  
Diels Alder ◽  
Keto Ester ◽  
Diels Alder Reaction ◽  
General Method

The intramolecular Diels–Alder reactivity of several trisubstituted cyclopentadienes is described and a general method for their preparation reported. In general, sidechain keto-ester functionality has an adverse effect on these internal cycloadditions.

ChemInform Abstract: First Evidence of a Chair-Boat-Boat Transition State in the Transannular Diels-Alder Reaction.

ChemInform ◽  
2010 ◽  
Vol 25 (38) ◽  
pp. no-no
Author(s):  
Y. L. DORY ◽  
C. OUELLET ◽  
S. BERTHIAUME ◽  
A. FAVRE ◽  
P. DESLONGCHAMPS
Keyword(s):  
Transition State ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction
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