Organic Ions in the Gas Phase. XVII. A Bicyclic Doubly Hydrogen-Bridged Transition State in Decomposition of 6-Substituted Alkanoic Acids and Esters

1966 ◽  
Vol 88 (1) ◽  
pp. 56-60 ◽  
Author(s):  
Seymour Meyerson ◽  
L. C. Leitch
Keyword(s):  
Transition State ◽  
Gas Phase ◽  
Organic Ions ◽  
Alkanoic Acids

ChemInform Abstract: THE STRUCTURE AND REACTIVITY OF ORGANIC IONS IN GAS-PHASE RADIOLYSIS PART 8, THE C7H7(+) ION FROM TOLUENE AND ETHYLBENZENE

1974 ◽  
Vol 5 (36) ◽  
Author(s):  
NOBUO SAGI ◽  
YUKIO YAMAMOTO ◽  
KENJI NAGAOKA ◽  
SETSUO TAKAMUKU ◽  
HIROSHI SAKURAI
Keyword(s):  
Gas Phase ◽  
Organic Ions

Additions and Corrections - Organic Ions in the Gas Phase. VII. Tropylium Ion from Benzyl Chloride and Benzyl Alcohol

1960 ◽  
Vol 82 (24) ◽  
pp. 6427-6427
Author(s):  
Seymour Meyerson ◽  
Paul Rylander ◽  
Ernest Eliel ◽  
John McCollum
Keyword(s):  
Benzyl Alcohol ◽  
Gas Phase ◽  
Benzyl Chloride ◽  
Organic Ions

Organic Ions in the Gas Phase. V. C6H5+ Ion from Toluene

1957 ◽  
Vol 27 (5) ◽  
pp. 1116-1117 ◽  
Author(s):  
Paul N. Rylander ◽  
Seymour Meyerson
Keyword(s):  
Gas Phase ◽  
Organic Ions

STRUCTURE AND REACTIVITY OF ORGANIC IONS IN GAS-PHASE RADIOLYSIS. IV. THE C7H7+ION FROM CYCLOHEPTATRIENE

1973 ◽  
Vol 2 (12) ◽  
pp. 1303-1306 ◽  
Author(s):  
Setsuo Takamuku ◽  
Katsuyoshi Nakamura ◽  
Kenji Nagaoka ◽  
Hiroshi Sakurai
Keyword(s):  
Gas Phase ◽  
Organic Ions

Towards a general scheme for estimating the heats of formation of organic ions in the gas phase. Part I. Odd-electron cations

1981 ◽  
Vol 59 (1) ◽  
pp. 80-93 ◽  
Author(s):  
John L. Holmes ◽  
Mervin Fingas ◽  
F. P. Lossing
Keyword(s):  
Gas Phase ◽  
General Scheme ◽  
Double Bond Position ◽  
Heats Of Formation ◽  
Organic Cations ◽  
Aliphatic Aldehydes ◽  
Aliphatic Ketones ◽  
Alkanoic Acids ◽  
Correction Terms ◽  
Aliphatic Ethers

It is shown that gas-phase heats of formation of homologous odd-electron organic cations can be well represented by an equation of the form ΔHf[ion]+• = A − Bn + C/n, where A, B, and C are constants and n is the total number of atoms in the molecule. Values for A, B, and C have been determined for the linear homologous series: alkanes, olefins, alkynes, alkanols, aliphatic ethers, aliphatic aldehydes, aliphatic ketones, alkanoic acids, alkyl chlorides, bromides, and iodides. For each of these series, correction terms for chain branching, double-bond position, and asymmetry effects are also given. These equations can be applied to molecules containing 40 or more atoms. The data base for this work is also presented.

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