The Binuclear Iridium(II) Hydride Complex [(C5Me5)Ir(μ-H)]2:  A Novel Base for Reversible Deprotonation of Acidic Organic Compounds and a Unique Catalyst for C−C Bond Cleavage of Aromatic 1,2-Diols and Michael Additions

2001 ◽  
Vol 123 (24) ◽  
pp. 5812-5813 ◽  
Author(s):  
Zhaomin Hou ◽  
Take-aki Koizumi ◽  
Akira Fujita ◽  
Hiroshi Yamazaki ◽  
Yasuo Wakatsuki
Keyword(s):  
Organic Compounds ◽  
Bond Cleavage ◽  
Hydride Complex ◽  
Michael Additions

Energetics of cellulose and cyclodextrin glycosidic bond cleavage

2017 ◽  
Vol 2 (2) ◽  
pp. 201-214 ◽  
Author(s):  
Cheng Zhu ◽  
Christoph Krumm ◽  
Gregory G. Facas ◽  
Matthew Neurock ◽  
Paul J. Dauenhauer
Keyword(s):  
High Temperature ◽  
Volatile Organic Compounds ◽  
Organic Compounds ◽  
Bond Cleavage ◽  
Thermochemical Conversion ◽  
Lignocellulosic Materials ◽  
Renewable Chemicals ◽  
Volatile Organic ◽  
Glycosidic Bond Cleavage ◽  
Long Chain

Thermochemical conversion of lignocellulosic materials for production of biofuels and renewable chemicals utilizes high temperature to thermally decompose long-chain cellulose to volatile organic compounds.

Investigations of Iridium-Mediated Reversible C−H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex

2009 ◽  
Vol 131 (24) ◽  
pp. 8603-8613 ◽  
Author(s):  
Wesley H. Bernskoetter ◽  
Susan Kloek Hanson ◽  
Sara K. Buzak ◽  
Zoe Davis ◽  
Peter S. White ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Hydride Complex

scholarly journals The Mechanism of N–N Double Bond Cleavage by an Iron(II) Hydride Complex

2016 ◽  
Vol 138 (37) ◽  
pp. 12112-12123 ◽  
Author(s):  
Sarina M. Bellows ◽  
Nicholas A. Arnet ◽  
Prabhuodeyara M. Gurubasavaraj ◽  
William W. Brennessel ◽  
Eckhard Bill ◽  
...  
Keyword(s):  
Double Bond ◽  
Bond Cleavage ◽  
Hydride Complex

scholarly journals Borane B−C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N−N Bond Cleavage by the Hydridoborate Product

2007 ◽  
Vol 26 (13) ◽  
pp. 3217-3226 ◽  
Author(s):  
Ying Yu ◽  
William W. Brennessel ◽  
Patrick L. Holland
Keyword(s):  
Bond Cleavage ◽  
Hydride Complex ◽  
Iron Hydride

NN Bond Cleavage by a Low-Coordinate Iron(II) Hydride Complex

2003 ◽  
Vol 125 (51) ◽  
pp. 15752-15753 ◽  
Author(s):  
Jeremy M. Smith ◽  
Rene J. Lachicotte ◽  
Patrick L. Holland
Keyword(s):  
Bond Cleavage ◽  
Hydride Complex
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