Studies on Ion Exchange Resins. VIII. Activity Coefficients of Diffusible Ions in Various Cation-exchange Resins

1953 ◽  
Vol 75 (14) ◽  
pp. 3539-3543 ◽  
Author(s):  
Harry P. Gregor ◽  
Melvin H. Gottlieb

1951 ◽  
Vol 6 (1) ◽  
pp. 20-32 ◽  
Author(s):  
Harry P Gregor ◽  
J.I Bregman ◽  
Fradelle Gutoff ◽  
Robert D Broadley ◽  
David E Baldwin ◽  
...  


RSC Advances ◽  
2017 ◽  
Vol 7 (13) ◽  
pp. 7555-7559 ◽  
Author(s):  
Joao M. J. M. Ravasco ◽  
Jaime A. S. Coelho ◽  
Svilen P. Simeonov ◽  
Carlos A. M. Afonso

Cr3+ modified readily available cation exchange resins were prepared and explored as heterogeneous bifunctional catalysts for dehydration of glucose to 5-hydroxymethylfurfural (HMF) in tetraethyl ammonium bromide (TEAB)/water as reaction medium.



1975 ◽  
Vol 9 (12) ◽  
pp. 783-787
Author(s):  
G. V. Samsonov ◽  
T. V. Atabekyan ◽  
O. P. Kolomeitsev ◽  
V. Ya. Vorob'eva


1970 ◽  
Vol 48 (6) ◽  
pp. 917-923 ◽  
Author(s):  
T. E. Gough ◽  
H. D. Sharma ◽  
N. Subramanian

The proton magnetic resonance spectra of cation-exchange resins of crosslinkage X1 to X16 in the H+, Li+, Na+, K +, Rb+, Cs+, and NH4+ forms have been recorded and the values of the molal chemical shift, δM+0, are found to be −0.321, −0.005, 0.041, 0.031, 0.028, 0.015, and 0.00 (assumed) p.p.m./mole, respectively, for the cations. These values are very nearly equal to those observed in corresponding aqueous solutions, indicating that ion–solvent interactions are similar in both the resin matrix and the aqueous solution. The temperature dependence of the chemical shift shows the same trend. The effective hydration numbers calculated from the temperature dependence are 2.0 (4.81 m) for the H+ form, 4.8 (3.25 m) and 3.6 (5.26 m) for the Na+ form, 4.4 (3.9 m) for the K+ form, and 2.4 (6.18 m) for the Cs+ form. The ions in the resin phase behave as solutions of strong electrolyte, which is consistent with the polyelectrolyte gel model for the ion-exchange resin.



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