scholarly journals Bifunctional Cr3+ modified ion exchange resins as efficient reusable catalysts for the production and isolation of 5-hydroxymethylfurfural from glucose

RSC Advances ◽  
2017 ◽  
Vol 7 (13) ◽  
pp. 7555-7559 ◽  
Author(s):  
Joao M. J. M. Ravasco ◽  
Jaime A. S. Coelho ◽  
Svilen P. Simeonov ◽  
Carlos A. M. Afonso

Cr3+ modified readily available cation exchange resins were prepared and explored as heterogeneous bifunctional catalysts for dehydration of glucose to 5-hydroxymethylfurfural (HMF) in tetraethyl ammonium bromide (TEAB)/water as reaction medium.

1951 ◽  
Vol 6 (1) ◽  
pp. 20-32 ◽  
Author(s):  
Harry P Gregor ◽  
J.I Bregman ◽  
Fradelle Gutoff ◽  
Robert D Broadley ◽  
David E Baldwin ◽  
...  

1975 ◽  
Vol 9 (12) ◽  
pp. 783-787
Author(s):  
G. V. Samsonov ◽  
T. V. Atabekyan ◽  
O. P. Kolomeitsev ◽  
V. Ya. Vorob'eva

1970 ◽  
Vol 48 (6) ◽  
pp. 917-923 ◽  
Author(s):  
T. E. Gough ◽  
H. D. Sharma ◽  
N. Subramanian

The proton magnetic resonance spectra of cation-exchange resins of crosslinkage X1 to X16 in the H+, Li+, Na+, K +, Rb+, Cs+, and NH4+ forms have been recorded and the values of the molal chemical shift, δM+0, are found to be −0.321, −0.005, 0.041, 0.031, 0.028, 0.015, and 0.00 (assumed) p.p.m./mole, respectively, for the cations. These values are very nearly equal to those observed in corresponding aqueous solutions, indicating that ion–solvent interactions are similar in both the resin matrix and the aqueous solution. The temperature dependence of the chemical shift shows the same trend. The effective hydration numbers calculated from the temperature dependence are 2.0 (4.81 m) for the H+ form, 4.8 (3.25 m) and 3.6 (5.26 m) for the Na+ form, 4.4 (3.9 m) for the K+ form, and 2.4 (6.18 m) for the Cs+ form. The ions in the resin phase behave as solutions of strong electrolyte, which is consistent with the polyelectrolyte gel model for the ion-exchange resin.


OENO One ◽  
2006 ◽  
Vol 40 (4) ◽  
pp. 223 ◽  
Author(s):  
Helena Mira ◽  
Patricia Leite ◽  
Jorge Manuel Ricardo-da-Silva ◽  
António Sérgio Curvelo-Garcia

<p style="text-align: justify;">The application of the cation exchange and double cation-anion exchange resins, regarding the wine tartrate stabilization, without previous treatment of wine by cold has been studied as well as their influence in phenolic, mineral and organic acid composition. The R1 resin was used in Mg2+, Na+ and H+ form, the R2 resin was always used in H+ form, and the R3 was used in OH- form. The eluted wine was assembled with untreated wine to obtain stable wine. The R2 resin showed to be more efficient to enhance the tartrate stabilization than R1 in Mg2+ form; however in H+ form, the behaviour of both resins was quite similar. The tartrate stabilization results to double cation anion exchange were similar to the results obtained with cation exchange.</p>


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