Factors Determining the Course and Mechanism of Grignard Reactions. XIV. Replacement of Halogen Atoms of Aromatic Halides with Hydrogen Atoms by the Action of Grignard Reagents and Cobaltous Chloride

1944 ◽  
Vol 66 (3) ◽  
pp. 481-482 ◽  
Author(s):  
M. S. Kharasch ◽  
D. C. Sayles ◽  
E. K. Fields
Keyword(s):  
Grignard Reagents ◽  
Hydrogen Atoms ◽  
Cobaltous Chloride ◽  
Halogen Atoms ◽  
Grignard Reactions

Displacement of Nuclear Halogen Atoms in Hindered Aryl Ketones by the Action of Grignard Reagents

1954 ◽  
Vol 76 (20) ◽  
pp. 5119-5121
Author(s):  
Reynold C. Fuson ◽  
William S. Friedlander ◽  
George W. Parshall
Keyword(s):  
Grignard Reagents ◽  
Halogen Atoms ◽  
Aryl Ketones

scholarly journals The Effect of β‐Hydrogen Atoms on Iron Speciation in Cross‐Couplings with Simple Iron Salts and Alkyl Grignard Reagents

2019 ◽  
Vol 131 (9) ◽  
pp. 2795-2799 ◽  
Author(s):  
Jeffrey D. Sears ◽  
Salvador B. Muñoz ◽  
Stephanie L. Daifuku ◽  
Ari A. Shaps ◽  
Stephanie H. Carpenter ◽  
...  
Keyword(s):  
Grignard Reagents ◽  
Iron Speciation ◽  
Hydrogen Atoms ◽  
Iron Salts

Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions

2020 ◽  
Vol 56 (9) ◽  
pp. 1381-1384 ◽  
Author(s):  
Lingyi Shen ◽  
Yanxia Zhao ◽  
Dihua Dai ◽  
Ying-Wei Yang ◽  
Biao Wu ◽  
...  
Keyword(s):  
Grignard Reagents ◽  
Alkyl Chains ◽  
Grignard Reactions

Grignard reagents with linear alkyl chains are encapsulated and stabilized by pillar[5]arene while preserving their reactivity in Grignard reactions.

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