The Metathesis-Facilitated Synthesis of Terminal Ruthenium Carbide Complexes:  A Unique Carbon Atom Transfer Reaction

2002 ◽  
Vol 124 (8) ◽  
pp. 1580-1581 ◽  
Author(s):  
Robert G. Carlson ◽  
Melanie A. Gile ◽  
Joseph A. Heppert ◽  
Mark H. Mason ◽  
Douglas R. Powell ◽  
...  
Keyword(s):  
Carbon Atom ◽  
Transfer Reaction ◽  
Atom Transfer

Sulfamides Direct Radical-Mediated Chlorination of Aliphatic C–H Bonds

2019 ◽  
Author(s):  
Melanie Short ◽  
Mina Shehata ◽  
Matthew Sanders ◽  
Jennifer Roizen
Keyword(s):  
Hydrogen Atom ◽  
Transfer Reaction ◽  
Hydrogen Atom Transfer ◽  
Chain Propagation ◽  
Propagation Mechanism ◽  
Atom Transfer ◽  
Radical Chain ◽  
Radical Intermediates ◽  
Transfer Processes ◽  
Unusual Position

Sulfamides guide intermolecular chlorine transfer to gamma-C(sp<sup>3</sup>) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp<sup>3</sup>)-H bonds.

Sulfamides Direct Radical-Mediated Chlorination of Aliphatic C–H Bonds

2019 ◽  
Author(s):  
Melanie Short ◽  
Mina Shehata ◽  
Matthew Sanders ◽  
Jennifer Roizen
Keyword(s):  
Hydrogen Atom ◽  
Transfer Reaction ◽  
Hydrogen Atom Transfer ◽  
Chain Propagation ◽  
Propagation Mechanism ◽  
Atom Transfer ◽  
Radical Chain ◽  
Radical Intermediates ◽  
Transfer Processes ◽  
Unusual Position

Sulfamides guide intermolecular chlorine transfer to gamma-C(sp<sup>3</sup>) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp<sup>3</sup>)-H bonds.

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

The important role of an unpaired d-electron for terminal oxygen atom transfer reaction of the (hydroperoxo) iron(III) compound

Polyhedron ◽  
2003 ◽  
Vol 22 (2) ◽  
pp. 293-297 ◽  
Author(s):  
Yuzo Nishida ◽  
Sayo Ito ◽  
Satoshi Nishino
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Terminal Oxygen Atom ◽  
Atom Transfer ◽  
Oxygen Atom Transfer

Hydrogen-atom transfer reaction from triplet 2-naphthylammonium ion to ground-state aromatic ketones

1983 ◽  
Vol 101 (6) ◽  
pp. 598-602 ◽  
Author(s):  
Haruo Shizuka ◽  
Masaru Fukushima
Keyword(s):  
Hydrogen Atom ◽  
Ground State ◽  
Transfer Reaction ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Aromatic Ketones

Intramolecular 1,5-hydrogen atom transfer reaction promoted by phosphoramidyl and carbamoyl radicals: synthesis of 2-amino-C-glycosides

2007 ◽  
Vol 48 (36) ◽  
pp. 6384-6388 ◽  
Author(s):  
Cosme G. Francisco ◽  
Antonio J. Herrera ◽  
Ángeles Martín ◽  
Inés Pérez-Martín ◽  
Ernesto Suárez
Keyword(s):  
Hydrogen Atom ◽  
Transfer Reaction ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer
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