Sulfamides Direct Radical-Mediated Chlorination of Aliphatic C–H Bonds
Keyword(s):
Sulfamides guide intermolecular chlorine transfer to gamma-C(sp<sup>3</sup>) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp<sup>3</sup>)-H bonds.
2019 ◽
2019 ◽
2019 ◽
Keyword(s):
2020 ◽
Hydrogen-atom transfer reaction from triplet 2-naphthylammonium ion to ground-state aromatic ketones
1983 ◽
Vol 101
(6)
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pp. 598-602
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Keyword(s):
2007 ◽
Vol 48
(36)
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pp. 6384-6388
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1991 ◽
Vol 95
(14)
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pp. 5489-5495
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Keyword(s):
2018 ◽
Vol 57
(10)
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pp. 2712-2715
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Keyword(s):