scholarly journals Investigating Inner-Sphere Reorganization via Secondary Kinetic Isotope Effects in the C−H Cleavage Reaction Catalyzed by Soybean Lipoxygenase: Tunneling in the Substrate Backbone as Well as the Transferred Hydrogen

2011 ◽  
Vol 133 (3) ◽  
pp. 430-439 ◽  
Author(s):  
Matthew P. Meyer ◽  
Judith P. Klinman
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Soybean Lipoxygenase ◽  
Cleavage Reaction ◽  
Kinetic Isotope ◽  
Inner Sphere

Large Deuterium Kinetic Isotope Effects in Soybean Lipoxygenase

1996 ◽  
pp. 116-137
Author(s):  
Chi-Ching Hwang ◽  
Charles Grissom
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Soybean Lipoxygenase ◽  
Kinetic Isotope

scholarly journals Kinetic isotope effects in the oxidation of arachidonic acid by soybean lipoxygenase-1

2008 ◽  
Vol 18 (22) ◽  
pp. 5959-5962 ◽  
Author(s):  
Cyril Jacquot ◽  
Sheng Peng ◽  
Wilfred A. van der Donk
Keyword(s):  
Arachidonic Acid ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Soybean Lipoxygenase ◽  
Kinetic Isotope

scholarly journals Comparative kinetic isotope effects on first- and second-order rate constants of soybean lipoxygenase variants uncover a substrate-binding network

2019 ◽  
Vol 294 (48) ◽  
pp. 18069-18076 ◽  
Author(s):  
Shenshen Hu ◽  
Adam R. Offenbacher ◽  
Edbert D. Lu ◽  
Judith P. Klinman
Keyword(s):  
Rate Constants ◽  
Substrate Binding ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Second Order ◽  
Soybean Lipoxygenase ◽  
Order Rate ◽  
Kinetic Isotope

scholarly journals Inner Sphere and Outer Sphere Electron Transfer to Methyl Iodide. Deuterium and 13C Kinetic Isotope Effects.

1996 ◽  
Vol 50 ◽  
pp. 90-93 ◽  
Author(s):  
Torkil Holm ◽  
Ingolf Crossland ◽  
Hans Toftlund ◽  
Jon Songstad ◽  
Markku Leskelä ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Methyl Iodide ◽  
Isotope Effects ◽  
Outer Sphere ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Inner Sphere ◽  
Outer Sphere Electron Transfer

Primary and secondary kinetic isotope effects in proton (H+/D+) and chloronium ion (35Cl+/37Cl+) affinities

2001 ◽  
Vol 36 (10) ◽  
pp. 1140-1148 ◽  
Author(s):  
F�bio Cesar Gozzo ◽  
Marcos N. Eberlin
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

Theoretical Simulations of Heavy-Atom Kinetic Isotope Effects in Aliphatic Claisen Rearrangement

2020 ◽  
Vol 124 (51) ◽  
pp. 10678-10686
Author(s):  
Yuqing Xu ◽  
Kin-Yiu Wong ◽  
Meishan Wang ◽  
Desheng Liu ◽  
Wenkai Zhao ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Isotope Effects ◽  
Heavy Atom ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope ◽  
Theoretical Simulations
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