Multiple-Site Concerted Proton–Electron Transfer Reactions of Hydrogen-Bonded Phenols Are Nonadiabatic and Well Described by Semiclassical Marcus Theory

Joel N. Schrauben; Mauricio Cattaneo; Thomas C. Day; Adam L. Tenderholt; James M. Mayer

doi:10.1021/ja305668h

Multiple-Site Concerted Proton–Electron Transfer Reactions of Hydrogen-Bonded Phenols Are Nonadiabatic and Well Described by Semiclassical Marcus Theory

Journal of the American Chemical Society ◽

10.1021/ja305668h ◽

2012 ◽

Vol 134 (40) ◽

pp. 16635-16645 ◽

Cited By ~ 60

Author(s):

Joel N. Schrauben ◽

Mauricio Cattaneo ◽

Thomas C. Day ◽

Adam L. Tenderholt ◽

James M. Mayer

Keyword(s):

Electron Transfer ◽

Marcus Theory ◽

Transfer Reactions ◽

Multiple Site ◽

Electron Transfer Reactions ◽

Hydrogen Bonded

ChemInform Abstract: Electron-Transfer Reactions: Reactions of Indoles with Nitrosonium Ion. Application of the Marcus Theory. Crystal Structures of 1-Methyl-3,4-, -3,5- and -3,6-dinitro-2-phenylindoles.

ChemInform ◽

10.1002/chin.199331105 ◽

2010 ◽

Vol 24 (31) ◽

pp. no-no

Author(s):

L. EBERSON ◽

E. GIORGINI ◽

L. GRECI ◽

G. TOSI ◽

C. RIZZOLI ◽

...

Keyword(s):

Electron Transfer ◽

Crystal Structures ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Nitrosonium Ion

Electron Transfer Reactions in Organic Chemistry. V. Examination of Postulated Electron Transfer Processes Involving Anionic and Carbanionic Nucleophiles with the Aid of the Marcus Theory.

Acta Chemica Scandinavica ◽

10.3891/acta.chem.scand.38b-0439 ◽

1984 ◽

Vol 38b ◽

pp. 439-459 ◽

Cited By ~ 65

Author(s):

Lennart Eberson ◽

Rolf Carlson ◽

Kjell Undheim ◽

Lars Mörch ◽

Torbjörn Norin

Keyword(s):

Organic Chemistry ◽

Electron Transfer ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Transfer Processes ◽

Electron Transfer Processes

Additions and Corrections - Kinetics of the Electron Transfer Reactions of Azaviolene Radical Ions. 2. Correlation with the Marcus Theory. The Question of Concerted Acid-Base Catalysis.

Journal of the American Chemical Society ◽

10.1021/ja00457a605 ◽

1977 ◽

Vol 99 (15) ◽

pp. 5228-5228

Author(s):

Claude Bernasconi ◽

Hsien-Chang Wang

Keyword(s):

Electron Transfer ◽

Marcus Theory ◽

Base Catalysis ◽

Transfer Reactions ◽

Radical Ions ◽

Acid Base ◽

Electron Transfer Reactions ◽

Kinetics Of

Activation parameters for homogeneous outer-sphere electron-transfer reactions. Comparisons between self-exchange and cross reactions using Marcus' theory

Inorganic Chemistry ◽

10.1021/ic50209a023 ◽

1980 ◽

Vol 19 (7) ◽

pp. 1936-1945 ◽

Cited By ~ 74

Author(s):

Michael J. Weaver ◽

Edmund L. Yee

Keyword(s):

Electron Transfer ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Cross Reactions ◽

Outer Sphere Electron Transfer

ChemInform Abstract: ELECTRON-TRANSFER REACTIONS IN ORGANIC CHEMISTRY. II. AN ANALYSIS OF ALKYL HALIDE REDUCTION BY ELECTRON-TRANSFER REAGENTS ON THE BASIS OF THE MARCUS THEORY

Chemischer Informationsdienst ◽

10.1002/chin.198303110 ◽

1983 ◽

Vol 14 (3) ◽

Author(s):

L. EBERSON

Keyword(s):

Organic Chemistry ◽

Electron Transfer ◽

Alkyl Halide ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions

ESR-Spectroscopic Investigation of the Homogeneous Electron Transfer Reactions between Substituted p-Phenylenediamines and Quinonediimines, and the Validity of Marcus' Theory. I. Measurements at 293 K

Berichte der Bunsengesellschaft für physikalische Chemie ◽

10.1002/bbpc.19840880403 ◽

1984 ◽

Vol 88 (4) ◽

pp. 325-334 ◽

Cited By ~ 61

Author(s):

Günter Grampp ◽

Walther Jaenicke

Keyword(s):

Electron Transfer ◽

Spectroscopic Investigation ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions

Experimental Validation of Marcus Theory for Outer-Sphere Heterogeneous Electron-Transfer Reactions: The Oxidation of Substituted 1,4-Phenylenediamines

ChemPhysChem ◽

10.1002/cphc.200400128 ◽

2004 ◽

Vol 5 (8) ◽

pp. 1234-1240 ◽

Cited By ~ 18

Author(s):

Antony D. Clegg ◽

Neil V. Rees ◽

Oleksiy V. Klymenko ◽

Barry A. Coles ◽

Richard G. Compton

Keyword(s):

Electron Transfer ◽

Experimental Validation ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Heterogeneous Electron Transfer

Kinetics of the electron-transfer reactions of azaviolene radical ions. 2. Correlation with the Marcus theory. The question of concerted acid-base catalysis

Journal of the American Chemical Society ◽

10.1021/ja00449a031 ◽

1977 ◽

Vol 99 (7) ◽

pp. 2214-2221 ◽

Cited By ~ 6

Author(s):

Claude F. Bernasconi ◽

Hsien-Chang Wang

Keyword(s):

Electron Transfer ◽

Marcus Theory ◽

Base Catalysis ◽

Transfer Reactions ◽

Radical Ions ◽

Acid Base ◽

Electron Transfer Reactions ◽

Kinetics Of

Are the current theories of electron transfer applicable to reactions in ionic liquids? An ESR-study on the TCNE/TCNE−˙ couple

Physical Chemistry Chemical Physics ◽

10.1039/c6cp01750a ◽

2016 ◽

Vol 18 (21) ◽

pp. 14442-14448 ◽

Cited By ~ 6

Author(s):

B. Y. Mladenova ◽

D. R. Kattnig ◽

B. Sudy ◽

P. Choto ◽

G. Grampp

Keyword(s):

Electron Transfer ◽

Ionic Liquids ◽

Marcus Theory ◽

Transfer Reactions ◽

Activation Barriers ◽

Electron Transfer Reactions ◽

Solvent Properties

Electron transfer reactions in ionic liquids are profoundly affected by solvent properties. The activation barriers cannot be generally accounted for by Marcus' theory.

Rate constants and activation parameters for outer-sphere electron-transfer reactions and comparisons with the predictions of Marcus theory

Journal of the American Chemical Society ◽

10.1021/ja00459a014 ◽

1977 ◽

Vol 99 (17) ◽

pp. 5615-5623 ◽

Cited By ~ 122

Author(s):

Mei Chou ◽

Carol Creutz ◽

Norman Sutin

Keyword(s):

Electron Transfer ◽

Rate Constants ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Outer Sphere Electron Transfer