Mechanistic Characterization of the HDV Genomic Ribozyme: Solvent Isotope Effects and Proton Inventories in the Absence of Divalent Metal Ions Support C75 as the General Acid

2008 ◽  
Vol 130 (44) ◽  
pp. 14504-14520 ◽  
Author(s):  
Andrea L. Cerrone-Szakal ◽  
Nathan A. Siegfried ◽  
Philip C. Bevilacqua
Keyword(s):  
Metal Ions ◽  
Isotope Effects ◽  
Divalent Metal ◽  
Divalent Metal Ions ◽  
General Acid ◽  
Solvent Isotope ◽  
Solvent Isotope Effects

Synthesis and characterization of bis(imino)pyridine complexes of divalent Mg and Zn

2016 ◽  
Vol 45 (14) ◽  
pp. 5989-5998 ◽  
Author(s):  
Thomas W. Myers ◽  
Tobias J. Sherbow ◽  
James C. Fettinger ◽  
Louise A. Berben
Keyword(s):  
Electronic Structure ◽  
Metal Ions ◽  
Torsion Angle ◽  
Divalent Metal ◽  
Synthesis And Characterization ◽  
Divalent Metal Ions ◽  
Structural Comparison ◽  
Bond Lengths ◽  
Pyridine Complexes

The synthesis and electronic structure of bis(imino)pyridine (I2P) complexes of the divalent metal ions, Zn(ii) and Mg(ii) are reported, and a correlation between the ligand Cim–Cpy bond lengths with the ligand torsion angle is described. Structural comparison with a new complex of Al(iii) and previously reported Al(iii) complexes is included.

Sign in / Sign up

Export Citation Format

Share Document