Self-Assembly of a Polyrotaxane Containing a Cyclic “Bead” in Every Structural Unit in the Solid State:  Cucurbituril Molecules Threaded on a One-Dimensional Coordination Polymer

1996 ◽  
Vol 118 (45) ◽  
pp. 11333-11334 ◽  
Author(s):  
Dongmok Whang ◽  
You-Moon Jeon ◽  
Jungseok Heo ◽  
Kimoon Kim
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Self Assembly ◽  
Structural Unit ◽  
One Dimensional

A smart sensing Zn (Ⅱ) coordination polymer based on a new viologen ligand exhibiting photochromic and thermochromic and multiple solid detection properties

2021 ◽  
Author(s):  
Heyi Zhang ◽  
Fangyuan He ◽  
Xiaonan Li ◽  
Zhi-Hui Wang ◽  
Hong Zhang
Keyword(s):  
Electron Transfer ◽  
Coordination Polymer ◽  
Self Assembly ◽  
Chain Structure ◽  
The Self ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Smart Sensing

Through the self-assembly of 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine] dichloride ligand, m-H2BDC and Zn(NO3)2·6H2O, a novel one-dimensional chain structure multifunctional coordination polymer was successfully synthesized. Due to electron transfer during irradiation and heating to...

scholarly journals Synthesis of a One-Dimensional Coordination Polymer of Nickel(II) Complex with a β-Oxodithioester Ligand

2017 ◽  
Vol 2017 ◽  
pp. 1-7
Author(s):  
Ricardo Rosas-Reyes ◽  
Yasmi Reyes-Ortega ◽  
T. Jesus Morales-Juarez ◽  
Virginia Gómez-Vidales ◽  
Ivan García-Orozco
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Elemental Analysis ◽  
Chloroform Solution ◽  
Magnetization Measurements ◽  
One Dimensional ◽  
H Nmr

Bis-[methyl-1-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S]nickel(II) 1 was prepared starting from methyl 2-hydroxycyclopent-1-encarbodithioate ligand (CPDT) and Ni(II), and catena-[(μ2-4,4′-Bipyril)-bis-(methyl-2-hydroxy-1-cyclopentene-2-dithiocarboxylate-O,S)]nickel(ΙΙ) 2 was prepared in good yields from 1 plus 4,4′-bipyridyl (bpy) by shish-kebab methodology. The structure of 1 was confirmed by FTIR, elemental analysis, 1H NMR, UV–vis in chloroform solution and in solid, XPS, and PXRD. Compound 2 was characterized by FTIR, elemental analysis, UV–vis in chloroform solution, and in solid, XPS, PXRD, ESR, and solid state magnetization measurements. The structure of the polymer was established mostly by PXRD, ESR, and magnetization.

scholarly journals catena-Poly[[trimethyltin(IV)]-μ-methylphenylphosphinato-κ2O:O′]

IUCrData ◽  
2017 ◽  
Vol 2 (10) ◽  
Author(s):  
Chunhua Fu ◽  
Rufen Zhang ◽  
Shaoliang Zhang
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Title Compound ◽  
Sodium Ethoxide ◽  
Chain Structure ◽  
Polymeric Chain ◽  
One Dimensional ◽  
Trigonal Bipyramidal ◽  
Trimethyltin Chloride ◽  
Distorted Trigonal Bipyramidal

A new trimethyltin(IV) coordination polymer, [Sn(CH3)3(C7H8O2P)], has been prepared by treatment of methylphenylphosphinic acid and trimethyltin chloride with sodium ethoxide in methanol. In the solid state, the title compound adopts an infinite one-dimensional polymeric chain structure with each SnIVatom adopting a distorted trigonal–bipyramidal geometry.

Structure and self-assembly synthesis of a novel heterometallic one-dimensional coordination polymer: {[Cu(II)(DETA)I·DMF]2[Pb2I6]} n

2006 ◽  
Vol 36 (7) ◽  
pp. 419-425 ◽  
Author(s):  
Haohong Li ◽  
Zhirong Chen ◽  
Junqian Li ◽  
Changcang Huang ◽  
Guangcan Xiao ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Self Assembly ◽  
One Dimensional

scholarly journals Ligand and solvent effects in the formation and self-assembly of a metallosupramolecular cage

2017 ◽  
Vol 41 (3) ◽  
pp. 1179-1185 ◽  
Author(s):  
N. N. Adarsh ◽  
Amarnath Chakraborty ◽  
Màrius Tarrés ◽  
Surjendu Dey ◽  
Fernando Novio ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Solvent Effects ◽  
Self Assembly ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray

A metallosupramolecular cage and a one-dimensional coordination polymer have been synthesized and structurally characterized by single crystal X-ray diffraction.

Self-assembly of a Novel One-dimensional Zigzag Coordination Polymer

2000 ◽  
Vol 11 (4) ◽  
pp. 251-254
Author(s):  
Ryan H. Groeneman ◽  
Jerry L. Atwood
Keyword(s):  
Coordination Polymer ◽  
Self Assembly ◽  
One Dimensional

Syntheses, Crystal Structures and Properties of Two New Manganese(II) Coordination Polymers with Tetrafluorophthalate Ligands

2013 ◽  
Vol 68 (3) ◽  
pp. 277-283 ◽  
Author(s):  
Sheng-Chun Chen ◽  
Jing Qin ◽  
Zhi-Hui Zhang ◽  
Xiao-Xiao Cai ◽  
Jian Gao ◽  
...  
Keyword(s):  
Solid State ◽  
Ir Spectroscopy ◽  
Self Assembly ◽  
The Self ◽  
Photoluminescence Properties ◽  
Double Chain ◽  
Triclinic Space Group ◽  
One Dimensional ◽  
Structures And Properties ◽  
Supramolecular Networks

Two new polymeric MnII complexes, {[Mn(1,2-BDC-F4)(H2O)3](EtOH)}n (1) and [Mn(1,2- BDC-F4)(H2O)2(DMF)]n (2), have been prepared from the reaction of MnII acetate with 3,4,5,6- tetrafluoro-benzene-1,2-dicarboxylic acid (1,2-H2BDC-F4) using different solvents, and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analysis, and single-crystal Xray structure analysis. Both complexes crystallize in the triclinic space group P1̄ and have similar one-dimensional double chain structures, consisting of a unique arrangement of 8-membered and 14- membered rings. The effects of solvent as ligand and/or guest on the self-assembly processes of the supramolecular networks and on their photoluminescence properties in the solid state are discussed.

Synthesis and Structural Characterization of a Monofunctionalized Phloroglucin-Derivative: A Precursor for Heterotrinuclear meta-Phenylene Bridged Complexes

2006 ◽  
Vol 61 (6) ◽  
pp. 753-757 ◽  
Author(s):  
Thorsten Glaser ◽  
Maik Heidemeier ◽  
Erich Krickemeyer ◽  
Hartmut Bögge
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Oxygen Atom ◽  
Structural Characterization ◽  
Magnetic Measurements ◽  
One Dimensional ◽  
Complex Forms ◽  
Neighboring Cation

As part of our synthetic efforts for new triplesalen derivatives, we reacted 2,4,6-triacetyl- 1,3,5-trihydroxybenzene (1) with excess Cu(ClO4)2 · 6H2O, imidazole, and ethylenediamine. However, not the triple ketimine derivative was formed but the mononuclear CuII complex [LCuII(ImH)]ClO4 · 0.5EtOH · 0.5H2O (HL = 6-(1-(2-aminoethylimino)ethyl)-2,4-diacetyl-1,3,5-trihydroxybenzene) with only one ketimine function. This complex forms a one-dimensional coordination polymer in the solid state through the apical binding of a keto-oxygen atom of one cation to the CuII ion of a neighboring cation. Magnetic measurements reveal the presence of weak antiferromagnetic intra-chain interactions

Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine

RSC Advances ◽  
2014 ◽  
Vol 4 (56) ◽  
pp. 29485-29492 ◽  
Author(s):  
Jian Zhang ◽  
Yaowen Li ◽  
Laibing Wang ◽  
Michiya Fujiki ◽  
Xiaopeng Li ◽  
...  
Keyword(s):  
Solid State ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Self Assembly ◽  
Power Conversion ◽  
Photovoltaic Property ◽  
Supramolecular Polymers ◽  
One Dimensional ◽  
Coating Technique

Fluorogallium tetra-tert-butylphthalocyanine (ttbPcGaF) can self-organize into well-ordered cofacial structures to obtain one-dimensional (1D) supramolecular polymers in the solid state using a solution-coating technique. The ttbPcGaF-based BHJ OSC provided a profoundly improved power conversion efficiency (PCE) of 0.41%.

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