Solvent-Cage Effect (Viscosity Dependence) as a Diagnostic Probe for the Mechanism of the Intramolecular Chemically Initiated Electron-Exchange Luminescence (CIEEL) Triggered from a Spiroadamantyl-Substituted Dioxetane

1999 ◽  
Vol 121 (5) ◽  
pp. 958-961 ◽  
Author(s):  
Waldemar Adam ◽  
Irena Bronstein ◽  
Alexei V. Trofimov ◽  
Rostislav F. Vasil'ev
Keyword(s):  
Electron Exchange ◽  
Cage Effect ◽  
Solvent Cage ◽  
Diagnostic Probe ◽  
Viscosity Dependence

Virial binding and the solvent cage effect

1994 ◽  
Vol 186 (1-2) ◽  
pp. 183-187
Author(s):  
A.A. Panjkov ◽  
E.R. Smith
Keyword(s):  
Cage Effect ◽  
Solvent Cage

Suppression of inhibition of substrate photodegradation by scavengers of hydroxyl radicals: the solvent-cage effect of bromide on nitrate photolysis

2008 ◽  
Vol 7 (4) ◽  
pp. 337-342 ◽  
Author(s):  
Radharani Das ◽  
Binay K. Dutta ◽  
Valter Maurino ◽  
Davide Vione ◽  
Claudio Minero
Keyword(s):  
Hydroxyl Radicals ◽  
Cage Effect ◽  
Solvent Cage

What Factors Control Dimerization of Coniferyl Alcohol?

Holzforschung ◽  
1999 ◽  
Vol 53 (6) ◽  
pp. 585-589 ◽  
Author(s):  
Carl J. Houtman
Keyword(s):  
Molecular Dynamics ◽  
Product Distribution ◽  
Coniferyl Alcohol ◽  
Cage Effect ◽  
Thermodynamic Control ◽  
Solvent Cage ◽  
Molecular Dynamics Calculations ◽  
Solvent Environment

Summary Data suggest that the dimerization of coniferyl alcohol is not under thermodynamic control. In this study, molecular dynamics calculations were used to estimate the effect of the solvent environment. In water, the coniferyl alcohol radicals were forced to associate by the formation of a solvent cage. In glycerol, the solvent cage effect appeared to be absent. These results suggest that in water, the product distribution of the dimers will be modified by interactions with the solvent. The computed results are consistent with experimental observations of coniferyl alcohol reactions in various solvents.

The distinct O2 quenching mechanism between fluorescence and phosphorescence for dyes adsorbed on silica gel

2020 ◽  
Vol 22 (46) ◽  
pp. 27144-27156
Author(s):  
Yu-Hsuan Cheng ◽  
Andrey Belyaev ◽  
Mei-Lin Ho ◽  
Igor O. Koshevoy ◽  
Pi-Tai Chou
Keyword(s):  
Silica Gel ◽  
Solid Phase ◽  
Cage Effect ◽  
Quenching Mechanism ◽  
Solvent Cage ◽  
Quenching Of Fluorescence ◽  
Fluorescence And Phosphorescence

In the solid phase, the lack of a solvent cage effect leads to the unstable CT states, rendering the decreased and thus a larger distinction between and , which therefore results in the efficient O2 quenching of fluorescence.

The Solvent Cage Effect:  Is There a Spin Barrier to Recombination of Transition Metal Radicals?

2007 ◽  
Vol 129 (19) ◽  
pp. 6255-6262 ◽  
Author(s):  
John D. Harris ◽  
Alan B. Oelkers ◽  
David R. Tyler
Keyword(s):  
Transition Metal ◽  
Cage Effect ◽  
Solvent Cage

Viscosity Dependence of the Chemically Induced Electron-Exchange Chemiluminescence Triggered from a Bicyclic Dioxetane

2000 ◽  
Vol 122 (36) ◽  
pp. 8631-8634 ◽  
Author(s):  
Waldemar Adam ◽  
Masakatsu Matsumoto ◽  
Alexei V. Trofimov
Keyword(s):  
Electron Exchange ◽  
Chemically Induced ◽  
Viscosity Dependence
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