scholarly journals Extension of Surface Organometallic Chemistry to Metal–Organic Frameworks: Development of a Well-Defined Single Site [(≡Zr–O−)W(═O)(CH2tBu)3] Olefin Metathesis Catalyst

2020 ◽  
Vol 142 (39) ◽  
pp. 16690-16703 ◽  
Author(s):  
Zeynabou Thiam ◽  
Edy Abou-Hamad ◽  
Busra Dereli ◽  
Lingmei Liu ◽  
Abdul-Hamid Emwas ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Olefin Metathesis ◽  
Metal Organic Frameworks ◽  
Single Site ◽  
Metathesis Catalyst ◽  
Metal Organic ◽  
Surface Organometallic Chemistry

scholarly journals A Step Towards Change: A Green Alternative for the Synthesis of Metal–Organic Frameworks

2021 ◽  
Author(s):  
Paola Marino ◽  
P. Rafael Donnarumma ◽  
Hudson de Aguiar Bicalho ◽  
Victor Quezada-Novoa ◽  
Hatem M. Titi ◽  
...  
Keyword(s):  
Environmental Impact ◽  
Human Health ◽  
Olefin Metathesis ◽  
Metal Organic Frameworks ◽  
Plant Oils ◽  
Renewable Feedstocks ◽  
Metal Organic ◽  
Industrial Settings

Metal–organic frameworks (MOFs) are traditionally synthesized using formamide solvents that are hazardous to human health and the environment. In order to alleviate the environmental impact of MOF synthesis in both academic and industrial settings, safer and greener solvent alternatives are desired. Herein, STEPOSOL® MET-10U (<i>N,N</i>-dimethyl-9-decenamide), a bioderived solvent produced <i>via</i> olefin metathesis using renewable feedstocks, such as plant oils, is explored as a solvent for the synthesis of a series of structurally diverse MOFs.

scholarly journals Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis

2018 ◽  
Vol 54 (32) ◽  
pp. 3989-3992 ◽  
Author(s):  
Keishi Yamamoto ◽  
Ka Wing Chan ◽  
Victor Mougel ◽  
Haruki Nagae ◽  
Hayato Tsurugi ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Olefin Metathesis ◽  
Reducing Agent ◽  
Highly Active ◽  
Species Formation ◽  
Surface Organometallic Chemistry

A well-defined silica-supported molybdenum dioxo species, (SiO)2Mo(O)2, prepared via Surface Organometallic Chemistry, is highly active in metathesis upon reaction with organosilicon reducing agent.

scholarly journals Molecular-level insight in supported olefin metathesis catalysts by combining surface organometallic chemistry, high throughput experimentation, and data analysis

2020 ◽  
Vol 11 (26) ◽  
pp. 6717-6723
Author(s):  
Jordan De Jesus Silva ◽  
Marco A. B. Ferreira ◽  
Alexey Fedorov ◽  
Matthew S. Sigman ◽  
Christophe Copéret
Keyword(s):  
Data Analysis ◽  
Organometallic Chemistry ◽  
High Throughput ◽  
Olefin Metathesis ◽  
Molecular Level ◽  
Structural Parameters ◽  
High Throughput Experimentation ◽  
Surface Organometallic Chemistry ◽  
Metathesis Catalysts

Combination of high-throughput experimentation, surface organometallic chemistry and data analysis helps to extract key structural parameters that facilitate olefin metathesis.

scholarly journals Front Cover: Design of Single-Site Photocatalysts by Using Metal-Organic Frameworks as a Matrix (Chem. Asian J. 14/2018)

2018 ◽  
Vol 13 (14) ◽  
pp. 1756-1756
Author(s):  
Meicheng Wen ◽  
Kohsuke Mori ◽  
Yasutaka Kuwahara ◽  
Taicheng An ◽  
Hiromi Yamashita
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Front Cover ◽  
Metal Organic ◽  
Cover Design

Well-Defined Molybdenum Oxo Alkyl Complex Supported on Silica by Surface Organometallic Chemistry: A Highly Active Olefin Metathesis Precatalyst

2017 ◽  
Vol 139 (6) ◽  
pp. 2144-2147 ◽  
Author(s):  
Nicolas Merle ◽  
Frédéric Le Quéméner ◽  
Yassine Bouhoute ◽  
Kai C. Szeto ◽  
Aimery De Mallmann ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Olefin Metathesis ◽  
Highly Active ◽  
Surface Organometallic Chemistry
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