Metal-Organic Frameworks as Single-Site Solid Catalysts for Asymmetric Reactions

2012 ◽  
Vol 52 (7) ◽  
pp. 591-603 ◽  
Author(s):  
Joseph M. Falkowski ◽  
Sophie Liu ◽  
Wenbin Lin
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Asymmetric Reactions ◽  
Solid Catalysts ◽  
Metal Organic

ChemInform Abstract: Metal-Organic Frameworks as Single-Site Solid Catalysts for Asymmetric Reactions

ChemInform ◽  
2012 ◽  
Vol 43 (49) ◽  
pp. no-no
Author(s):  
Joseph M. Falkowski ◽  
Sophie Liu ◽  
Wenbin Lin
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Asymmetric Reactions ◽  
Solid Catalysts ◽  
Metal Organic

scholarly journals Cobalt-Based Metal Organic Frameworks as Solids Catalysts for Oxidation Reactions

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 95
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Eva Montero Lanzuela ◽  
Sergio Navalon ◽  
Hermenegildo Garcia
Keyword(s):  
Aerobic Oxidation ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Acid Sites ◽  
Crystalline Lattice ◽  
Oxidation Reactions ◽  
Solid Catalysts ◽  
Long Term Stability ◽  
Metal Organic

Metal organic frameworks (MOFs) are porous crystalline solids whose frameworks are constituted by metal ions/nodes with rigid organic linkers leading to the formation of materials having high surface area and pore volume. One of the unique features of MOFs is the presence of coordinatively unsaturated metal sites in their crystalline lattice that can act as Lewis acid sites promoting organic transformations, including aerobic oxidation reactions of various substrates such as hydrocarbons, alcohols, and sulfides. This review article summarizes the existing Co-based MOFs for oxidation reactions organized according to the nature of substrates like hydrocarbon, alcohol, olefin, and water. Both aerobic conditions and peroxide oxidants are discussed. Emphasis is placed on comparing the advantages of using MOFs as solid catalysts with respect to homogeneous salts in terms of product selectivity and long-term stability. The final section provides our view on future developments in this field.

Metal-organic frameworks as emerging platform for supporting isolated single-site catalysts

Nano Today ◽  
2019 ◽  
Vol 27 ◽  
pp. 178-197 ◽  
Author(s):  
Wenshi Zhao ◽  
Guodong Li ◽  
Zhiyong Tang
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Metal Organic ◽  
Single Site Catalysts

scholarly journals Front Cover: Design of Single-Site Photocatalysts by Using Metal-Organic Frameworks as a Matrix (Chem. Asian J. 14/2018)

2018 ◽  
Vol 13 (14) ◽  
pp. 1756-1756
Author(s):  
Meicheng Wen ◽  
Kohsuke Mori ◽  
Yasutaka Kuwahara ◽  
Taicheng An ◽  
Hiromi Yamashita
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Front Cover ◽  
Metal Organic ◽  
Cover Design

Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts

2012 ◽  
Vol 48 (52) ◽  
pp. 6508 ◽  
Author(s):  
Joseph M. Falkowski ◽  
Sophie Liu ◽  
Cheng Wang ◽  
Wenbin Lin
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Open Channels ◽  
Asymmetric Cyclopropanation ◽  
Metal Organic

Catalysis and photocatalysis by metal organic frameworks

2018 ◽  
Vol 47 (22) ◽  
pp. 8134-8172 ◽  
Author(s):  
Amarajothi Dhakshinamoorthy ◽  
Zhaohui Li ◽  
Hermenegildo Garcia
Keyword(s):  
Metal Organic Frameworks ◽  
Organic Transformations ◽  
Solid Catalysts ◽  
Metal Organic

This review aims to provide different strategies employed to use MOFs as solid catalysts and photocatalysts in organic transformations.

Glucose Isomerization and Epimerization over Metal‐Organic Frameworks with Single‐Site Active Centers

ChemCatChem ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1903-1909 ◽  
Author(s):  
Qun‐Xing Luo ◽  
Yuan‐Bao Zhang ◽  
Long Qi ◽  
Susannah L. Scott
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Active Centers ◽  
Metal Organic ◽  
Glucose Isomerization

scholarly journals Metal–organic frameworks: A tunable platform to access single-site heterogeneous catalysts

2019 ◽  
Vol 586 ◽  
pp. 117214 ◽  
Author(s):  
Megan C. Wasson ◽  
Cassandra T. Buru ◽  
Zhijie Chen ◽  
Timur Islamoglu ◽  
Omar K. Farha
Keyword(s):  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Single Site ◽  
Metal Organic

scholarly journals Metal–organic and covalent organic frameworks as single-site catalysts

2017 ◽  
Vol 46 (11) ◽  
pp. 3134-3184 ◽  
Author(s):  
S. M. J. Rogge ◽  
A. Bavykina ◽  
J. Hajek ◽  
H. Garcia ◽  
A. I. Olivos-Suarez ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Covalent Organic Frameworks ◽  
Metal Organic ◽  
Single Site Catalysts

The potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly.

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