Experimental and Computational Studies of Palladium-Catalyzed Spirocyclization via a Narasaka–Heck/C(sp3 or sp2)–H Activation Cascade Reaction

2021 ◽  
Author(s):  
Wan-Xu Wei ◽  
Yuke Li ◽  
Ya-Ting Wen ◽  
Ming Li ◽  
Xue-Song Li ◽  
...  
Keyword(s):  
Cascade Reaction ◽  
Computational Studies ◽  
Palladium Catalyzed ◽  
Activation Cascade

Intermolecular C–H Amidation of Alkenes with Carbon Monoxide and Azides via Tandem Palladium Catalysis

Synthesis ◽  
2021 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Yang Wu ◽  
Feng Jin ◽  
Bao Xiaoguang ◽  
Ji-Bao Xia
Keyword(s):  
Carbon Monoxide ◽  
Palladium Catalysis ◽  
Computational Studies ◽  
Organic Azides ◽  
Reaction Proceeds ◽  
Palladium Catalyzed ◽  
Directing Group ◽  
And Control

An atom- and step-economic intermolecular multi-component palladium-catalyzed C–H amidation of alkenes with carbon monoxide and organic azides has been developed for the synthesis of alkenyl amides. The reaction proceeds efficiently without an ortho-directing group on the alkene substrates. Nontoxic dinitrogen is generated as the sole by-product. Computational studies and control experiments have revealed that the reaction takes place via an unexpected mechanism by tandem palladium catalysis.

ChemInform Abstract: Synthesis of Spiro Imines from Oximes by Palladium-Catalyzed Cascade Reaction.

ChemInform ◽  
2010 ◽  
Vol 32 (41) ◽  
pp. no-no
Author(s):  
Mitsuru Kitamura ◽  
Shazia Zaman ◽  
Koichi Narasaka
Keyword(s):  
Cascade Reaction ◽  
Palladium Catalyzed

Carbofluorination via a palladium-catalyzed cascade reaction

2013 ◽  
Vol 4 (3) ◽  
pp. 1216 ◽  
Author(s):  
Marie-Gabrielle Braun ◽  
Matthew H. Katcher ◽  
Abigail G. Doyle
Keyword(s):  
Cascade Reaction ◽  
Palladium Catalyzed

A palladium-catalyzed dehydrative N-benzylation/C–H benzylation cascade of 2-morpholinoanilines on water

2018 ◽  
Vol 20 (6) ◽  
pp. 1297-1305 ◽  
Author(s):  
Hidemasa Hikawa ◽  
Risa Ichinose ◽  
Shoko Kikkawa ◽  
Isao Azumaya
Keyword(s):  
Cascade Reaction ◽  
Synthetic Route ◽  
Benzyl Alcohols ◽  
Palladium Catalyzed

A strategy for the palladium-catalyzed dehydrative tandem benzylation of 2-morpholinoanilines with benzyl alcohols has been developed. This cascade reaction is devised as a straightforward and efficient synthetic route for N-(1,2-diphenylethyl)-2-morpholinoanilines.

Palladium-Catalyzed Cascade Reaction of o-Cyanobiaryls with Arylboronic Acids: Synthesis of 5-Arylidene-7-aryl-5H-dibenzo[c,e]azepines

2019 ◽  
Vol 21 (19) ◽  
pp. 7697-7701 ◽  
Author(s):  
Xinrong Yao ◽  
Yinlin Shao ◽  
Maolin Hu ◽  
Yuanzhi Xia ◽  
Tianxing Cheng ◽  
...  
Keyword(s):  
Cascade Reaction ◽  
Arylboronic Acids ◽  
Palladium Catalyzed

A palladium-catalyzed multi-component annulation approach towards the synthesis of phenanthrenes

2019 ◽  
Vol 17 (13) ◽  
pp. 3328-3332
Author(s):  
Juan Song ◽  
Songjiang Wang ◽  
Haisen Sun ◽  
Yuxuan Fan ◽  
Kang Xiao ◽  
...  
Keyword(s):  
Cascade Reaction ◽  
Palladium Catalyzed

An efficient palladium-catalyzed three-component cascade reaction has been developed for the facile construction of phenanthrene frameworks.

ChemInform Abstract: Highly Fluorescent, π-Extended Indenopyrido[2,1-a]isoindolone Derivatives Prepared by a Palladium-Catalyzed Cascade Reaction.

ChemInform ◽  
2013 ◽  
Vol 44 (38) ◽  
pp. no-no
Author(s):  
Zein el abidine Chamas ◽  
Enrico Marchi ◽  
Alberto Modelli ◽  
Yves Fort ◽  
Paola Ceroni ◽  
...  
Keyword(s):  
Cascade Reaction ◽  
Palladium Catalyzed
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