The Fixed Propeller-Like Conformation of Tetraphenylethylene that Reveals Aggregation-Induced Emission Effect, Chiral Recognition, and Enhanced Chiroptical Property

2016 ◽  
Vol 138 (36) ◽  
pp. 11469-11472 ◽  
Author(s):  
Jia-Bin Xiong ◽  
Hai-Tao Feng ◽  
Jian-Ping Sun ◽  
Wen-Zhao Xie ◽  
Dong Yang ◽  
...  
RSC Advances ◽  
2013 ◽  
Vol 3 (33) ◽  
pp. 14099 ◽  
Author(s):  
Wen-Hao Yu ◽  
Chao Chen ◽  
Ping Hu ◽  
Bi-Qin Wang ◽  
Carl Redshaw ◽  
...  

2022 ◽  
Author(s):  
Pingwu Du ◽  
Xinyu Zhang ◽  
Huiqing Liu ◽  
Guilin Zhuang ◽  
Shangfeng Yang

Herein we report a novel chiral bismacrocycle with unexpected dual emission and tunable aggregation-induced emission colors. A facile four-step synthesis strategy is developed to construct this rigid bismacrocycle, (1,4)[8]cycloparaphenylenophane (SCPP[8]), which possesses a 1,2,4,5-tetraphenylbenzene core locked by two intersecting polyphenylene-based macrocycles. The luminescent behavior of SCPP[8] shows the unique characteristics of both aggregation-caused quenching effect and aggrega-tion-induced emission (AIE) effect, inducing remarkable redshift emission including near white-light emission. SCPP[8] is configurationally stable and possesses a novel shape-persistent bismacrocycle scaffold with a high strain energy (up to 127.83 kcal/mol). In addition, SCPP[8] displays enhanced circularly polarized luminescence properties due to AIE effect.


2018 ◽  
Vol 47 (19) ◽  
pp. 7452-7476 ◽  
Author(s):  
Hai-Tao Feng ◽  
Ying-Xue Yuan ◽  
Jia-Bin Xiong ◽  
Yan-Song Zheng ◽  
Ben Zhong Tang

Syntheses, photophysical properties and applications of macrocycles and cages based on tetraphenylethylene with aggregation-induced emission (AIE) effect.


RSC Advances ◽  
2018 ◽  
Vol 8 (27) ◽  
pp. 14995-15000 ◽  
Author(s):  
Wenjuan Zhang ◽  
Hanxiao Yang ◽  
Nan Li ◽  
Na Zhao

A sensitive fluorescent probe (TPEQN-P) was designed and synthesized for detecting alkaline phosphatase and monitoring its enzymatic activity based on the specific aggregation-induced emission effect.


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