Open-Shell and Antiaromatic Character Induced by the Highly Symmetric Geometry of the Planar Heptalene Structure: Synthesis and Characterization of a Nonalternant Isomer of Bisanthene

2019 ◽  
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pp. 10165-10170 ◽  
Author(s):  
Akihito Konishi ◽  
Koki Horii ◽  
Daisuke Shiomi ◽  
Kazunobu Sato ◽  
Takeji Takui ◽  
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Ki Min Nam ◽  
Yong-Il Kim ◽  
Younghun Jo ◽  
Seung Mi Lee ◽  
Bog G. Kim ◽  
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2022 ◽  
Author(s):  
Ruth Weller ◽  
Markus Balmer ◽  
Carsten von Hänisch ◽  
Gunnar Werncke

The synthesis and characterization of the first homoleptic open-shell transition metal phosphinidenide is presented. By reacting [MnL2] (L = −N(SiMe3)2) with [(sIDipp)PK] (sIDipp = 1,3-bis(2,6-di-iso-propylphenyl)-imidazolidine-2-ylidene), the formation of [Mn{P(sIDipp)}2] instead...


2013 ◽  
Vol 36 ◽  
pp. 27-30 ◽  
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Guo-Ming Wang ◽  
Xiao Zhang ◽  
Jin-Hua Li ◽  
Zong-Hua Wang ◽  
Ying-Xia Wang ◽  
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2019 ◽  
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pp. 011104 ◽  
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Kateřina Tomanová ◽  
Václav Čuba ◽  
Mikhail G. Brik ◽  
Eva Mihóková ◽  
Rosana Martinez Turtos ◽  
...  

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