Synthesis of the Open-Shell 3d-Transition Metal(II) Bis(phosphinidenide) [Mn{P(sIDipp)}2]
The synthesis and characterization of the first homoleptic open-shell transition metal phosphinidenide is presented. By reacting [MnL2] (L = −N(SiMe3)2) with [(sIDipp)PK] (sIDipp = 1,3-bis(2,6-di-iso-propylphenyl)-imidazolidine-2-ylidene), the formation of [Mn{P(sIDipp)}2] instead...
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