Synthesis of the Open-Shell 3d-Transition Metal(II) Bis(phosphinidenide) [Mn{P(sIDipp)}2]

2022 ◽  
Author(s):  
Ruth Weller ◽  
Markus Balmer ◽  
Carsten von Hänisch ◽  
Gunnar Werncke

The synthesis and characterization of the first homoleptic open-shell transition metal phosphinidenide is presented. By reacting [MnL2] (L = −N(SiMe3)2) with [(sIDipp)PK] (sIDipp = 1,3-bis(2,6-di-iso-propylphenyl)-imidazolidine-2-ylidene), the formation of [Mn{P(sIDipp)}2] instead...

2019 ◽  
Vol 58 (4) ◽  
pp. 2354-2362 ◽  
Author(s):  
Assma Benkada ◽  
Helge Reinsch ◽  
Michael Poschmann ◽  
Jan Krahmer ◽  
Nicole Pienack ◽  
...  

2013 ◽  
Vol 25 (16) ◽  
pp. 9362-9364
Author(s):  
Feng-Ying Chai ◽  
Xin-Ying Zhang ◽  
Meng-Meng Zhao ◽  
Zheng-Kun Wang ◽  
Jiao-Long Meng ◽  
...  

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