scholarly journals Asymmetric Hydroboration of Heteroaryl Ketones by Aluminum Catalysis

2019 ◽  
Vol 141 (49) ◽  
pp. 19415-19423 ◽  
Author(s):  
Yury Lebedev ◽  
Iuliia Polishchuk ◽  
Bholanath Maity ◽  
Miguel Dinis Veloso Guerreiro ◽  
Luigi Cavallo ◽  
...  
Keyword(s):  
Asymmetric Hydroboration

ANIPE-Cu Catalyst Enables Highly Enantioselective Markovnikov Hydroboration of α-Olefins

Synlett ◽  
2020 ◽  
Author(s):  
Shi-Liang Shi ◽  
Yuan Cai
Keyword(s):  
Petrochemical Industry ◽  
Future Directions ◽  
Asymmetric Hydroboration ◽  
Terminal Alkenes ◽  
Cu Catalyst

AbstractAsymmetric hydroboration of simple and unactivated terminal alkenes (α-olefins), feedstock chemicals derived from the petrochemical industry, has not been efficiently realized for past decades. Using a bulky ANIPE ligand, we achieved a rare example of highly enantioselective copper-catalyzed Markovnikov hydroboration of α-olefins. The chiral secondary alkylboronic ester products were obtained in moderate to good yields and regioselectivities with excellent enantioselectivities.1 Introduction2 Conditions Optimization3 Substrate Scope4 Application5 Mechanistic Discussion6 Conclusions and Future Directions

New Insights on the Asymmetric Hydroboration of Perfluoroalkenes.

ChemInform ◽  
2004 ◽  
Vol 35 (26) ◽  
Author(s):  
Anna M. Segarra ◽  
Carmen Claver ◽  
Elena Fernandez
Keyword(s):  
Asymmetric Hydroboration

ChemInform Abstract: Cobalt-Catalyzed Asymmetric Hydroboration of Aryl Ketones with Pinacolborane.

ChemInform ◽  
2015 ◽  
Vol 46 (31) ◽  
pp. no-no
Author(s):  
Jun Guo ◽  
Jianhui Chen ◽  
Zhan Lu
Keyword(s):  
Asymmetric Hydroboration ◽  
Aryl Ketones

scholarly journals Parallel Kinetic Resolution of Intramolecular Furan Diels-Alder Cycloadducts via Asymmetric Hydroboration

2019 ◽  
Vol 2019 (43) ◽  
pp. 7223-7227 ◽  
Author(s):  
Tamara Fulgheri ◽  
Philip Cornwall ◽  
Andrew R. Turner ◽  
Joseph B. Sweeney ◽  
Duncan M. Gill
Keyword(s):  
Kinetic Resolution ◽  
Diels Alder ◽  
Asymmetric Hydroboration ◽  
Parallel Kinetic Resolution
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