Thermodynamic properties of binary mixtures containing sulfur amide. 2. Excess molar volumes of 1,4-dioxane + N,N-dimethylmethanesulfinamide and 1,4-dioxane + N-methylmethanesulfinamide

1987 ◽  
Vol 32 (2) ◽  
pp. 241-243 ◽  
Author(s):  
Pirkko Ruostesuo ◽  
Tuula Mattila
Keyword(s):  
Thermodynamic Properties ◽  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Molar Volumes

scholarly journals Excess molar volumes, partial molar volumes and isentropic compressibilities of binary systems (ionic liquid + alkanol)

2009 ◽  
Author(s):  
◽  
Precious N. Sibiya
Keyword(s):  
Thermodynamic Properties ◽  
Binary Mixtures ◽  
Intermolecular Interactions ◽  
Binary Systems ◽  
Excess Molar Volumes ◽  
Partial Molar Volumes ◽  
Isentropic Compressibility ◽  
Volume Data ◽  
Specific Chemical ◽  
Molar Volumes

The thermodynamic properties of binary liquid mixtures involving ionic liquids (ILs) with alcohols were determined. ILs are an important class of solvents since they are being investigated as environmentally benign solvents, because of their negligible vapour pressure, and as potential replacement solvents for volatile organic compounds (VOCs) currently used in industries. Alcohols were chosen for this study because they have hydrogen bonding and their interaction with ILs will help in understanding the intermolecular interactions. Also, their thermodynamic properties are used for the development of specific chemical processes. The excess molar volumes of binary mixtures of {1-ethyl-3-methylimidazolium ethylsulfate + methanol or 1-propanol or 2-propanol}, {trioctylmethylammonium bis (trifluoromethyl-sulfonyl) imide + methanol or ethanol or 1-propanol}, {1-buty-3-methylimidazolium methylsulfate + methanol or ethanol or 1-propanol} were calculated from experimental density values, at T = (298.15, 303.15 and 313.15) K. The Redlich-Kister smoothing polynomial was fitted to the excess molar volume data. The partial molar volumes of the binary mixtures {1-ethyl-3-methylimidazolium ethylsulfate + methanol or 1-propanol or 2-propanol}, {trioctylmethylammonium bis (trifluoromethyl-sulfonyl) imide + methanol or ethanol or 1-propanol}, {1-buty-3-methylimidazolium methylsulfate + methanol or ethanol or 1-propanol} were calculated from the Redlich-Kister coefficients, at T = (298.15, 303.15 and 313.15) K. This information was used to better understand the intermolecular interactions with each solvent at infinite dilution. iii The isentropic compressibility of {trioctylmethylammonium bis (trifluoromethyl-sulfonyl) imide + methanol or ethanol or 1-propanol}, were calculated from the speed of sound data at T = 298.15 K.

Excess molar volumes of n-alkanol (C1-C5) binary mixtures with acetonitrile

1986 ◽  
Vol 31 (2) ◽  
pp. 152-154 ◽  
Author(s):  
Jagjit S. Sandhu ◽  
Ashok K. Sharma ◽  
Ramesh K. Wadi
Keyword(s):  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Molar Volumes

scholarly journals Prediction of excess molar volumes of selected binary mixtures from refractive index data

2014 ◽  
Vol 79 (6) ◽  
pp. 707-718 ◽  
Author(s):  
Jelena Vuksanovic ◽  
Divna Bajic ◽  
Gorica Ivanis ◽  
Emila Zivkovic ◽  
Ivona Radovic ◽  
...  
Keyword(s):  
Refractive Index ◽  
Binary Mixtures ◽  
Excess Molar Volumes ◽  
Mixing Rules ◽  
Mixing Rule ◽  
Molar Volumes ◽  
Index Data ◽  
Peg 400 ◽  
Benzene Toluene ◽  
Refractive Index Data

The excess molar volumes of twenty two binary mixtures containing various groups of organic compounds: alcohols (ethanol, 1-propanol, 1,2-propanediol, 1,3-propanediol and glycerol), ketone (acetone), ester (butyl lactate), lactam (N-methyl-2-pyrrolidone), PEGs (PEG 200, PEG 400) and aromatics (benzene, toluene and pyridine) were predicted from the refractive index data, using three types of equations coupled with several mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and Oster. The obtained results were analysed in terms of the applied equation and mixing rule and the nature of interactions between the mixtures? components.

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