Metal Ion Catalysis in Nucleophilic Substitution Reactions Promoted by Complexes of Polyether Ligands with Alkali Metal Salts

Alessandro Gobbi; Dario Landini; Angelamaria Maia; Daniela Secci

doi:10.1021/jo00123a036

Metal Ion Catalysis in Nucleophilic Substitution Reactions Promoted by Complexes of Polyether Ligands with Alkali Metal Salts

The Journal of Organic Chemistry ◽

10.1021/jo00123a036 ◽

1995 ◽

Vol 60 (18) ◽

pp. 5954-5957 ◽

Cited By ~ 12

Author(s):

Alessandro Gobbi ◽

Dario Landini ◽

Angelamaria Maia ◽

Daniela Secci

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Metal Ion ◽

Metal Salts ◽

Alkali Metal Salts ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions ◽

Metal Ion Catalysis

Alkali Metal Ion Catalysis and Inhibition in Nucleophilic Substitution Reactions of 3,4-Dinitrophenyl Diphenylphosphinothioate with Alkali Metal Ethoxides in Anhydrous Ethanol: Effect of Changing Electrophilic Center from P=O to P=S

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2011.32.7.2423 ◽

2011 ◽

Vol 32 (7) ◽

pp. 2423-2427 ◽

Cited By ~ 3

Author(s):

Jun-Sung An ◽

Gil NamKoong ◽

Ji-Sun Kang ◽

Ik-Hwan Um

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Metal Ion ◽

Anhydrous Ethanol ◽

Substitution Reactions ◽

Alkali Metal Ion ◽

Nucleophilic Substitution Reactions ◽

Metal Ion Catalysis ◽

Ethanol Effect

Alkali-Metal Ion Catalysis in Nucleophilic Substitution Reactions of 5-Nitro-8-quinolyl Picolinate with Alkali Metal Ethoxides: Effect of Modification of Nonleaving Group from Benzoyl to Picolinyl on Reactivity and Transition State Structure

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2014.35.5.1506 ◽

2014 ◽

Vol 35 (5) ◽

pp. 1506-1510 ◽

Cited By ~ 1

Author(s):

Seong Hoon Jeon ◽

Jung Hwan Yoon ◽

Min-Young Kim ◽

Ik-Hwan Um

Keyword(s):

Alkali Metal ◽

Transition State ◽

Nucleophilic Substitution ◽

Metal Ion ◽

State Structure ◽

Transition State Structure ◽

Substitution Reactions ◽

Alkali Metal Ion ◽

Nucleophilic Substitution Reactions ◽

Metal Ion Catalysis

Alkali Metal Ion Catalysis in Nucleophilic Substitution Reactions of 5-Nitro-8-quinolyl Benzoate with Alkali Metal Ethoxides in Anhydrous Ethanol: Unusually High Na+Ion Selectivity

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2008.29.1.117 ◽

2008 ◽

Vol 29 (1) ◽

pp. 117-121 ◽

Cited By ~ 8

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Metal Ion ◽

Ion Selectivity ◽

Anhydrous Ethanol ◽

Substitution Reactions ◽

Alkali Metal Ion ◽

Nucleophilic Substitution Reactions ◽

Metal Ion Catalysis

Metal Ion Catalysis and Inhibition in Nucleophilic Substitution Reactions of 4-Nitrophenyl Nicotinate and Isonicotinate with Alkali Metal Ethoxides in Anhydrous Ethanol

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2011.32.6.1951 ◽

2011 ◽

Vol 32 (6) ◽

pp. 1951-1956 ◽

Cited By ~ 2

Author(s):

Seo-Young Choi ◽

Yeon-Ju Hong ◽

Ik-Hwan Um

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Metal Ion ◽

Anhydrous Ethanol ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions ◽

Metal Ion Catalysis

One molecule of ionic liquid and tert-alcohol on a polystyrene-support as catalysts for efficient nucleophilic substitution including fluorination

Organic & Biomolecular Chemistry ◽

10.1039/c4ob01781a ◽

2014 ◽

Vol 12 (45) ◽

pp. 9264-9271 ◽

Cited By ~ 17

Author(s):

Sandip S. Shinde ◽

Sunil N. Patil

Keyword(s):

Ionic Liquid ◽

Alkali Metal ◽

Nucleophilic Substitution ◽

Metal Salts ◽

Alkali Metal Salts ◽

Efficient Catalyst ◽

Highly Efficient ◽

Polystyrene Support

The tert-alcohol and ionic liquid solvents in one molecule [mim-tOH][OMs] was immobilized on polystyrene and reported to be a highly efficient catalyst in aliphatic nucleophilic substitution using alkali metal salts.

Nucleophilic Substitution Reactions at Phosphorus with Alkali Metal Acetylides

Category 3, Compounds with Four and Three Carbon Heteroatom Bonds ◽

10.1055/sos-sd-024-01077 ◽

2006 ◽

pp. 1

Author(s):

K. M. Pietrusiewicz ◽

M. Stankevič

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions

Effect of Alkali Metal Ions on Nucleophilic Substitution Reactions of 4-Nitrophenyl X-Substituted Benzoates with Alkali Metal Ethoxides in Anhydrous Ethanol

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2010.31.02.303 ◽

2010 ◽

Vol 31 (2) ◽

pp. 303-308 ◽

Cited By ~ 10

Author(s):

Jin-A Seo ◽

Song-I Kim ◽

Yeon-Ju Hong ◽

Ik-Hwan Um

Keyword(s):

Alkali Metal ◽

Metal Ions ◽

Nucleophilic Substitution ◽

Anhydrous Ethanol ◽

Alkali Metal Ions ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions

Metal Ion Catalysis in Nucleophilic Substitution Reaction of 4-Nitrophenyl Picolinate with Alkali Metal Ethoxides in Anhydrous Ethanol

Bulletin of the Korean Chemical Society ◽

10.5012/bkcs.2010.31.9.2483 ◽

2010 ◽

Vol 31 (9) ◽

pp. 2483-2487 ◽

Cited By ~ 6

Author(s):

Yeon-Ju Hong ◽

Song-I Kim ◽

Ik-Hwan Um

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Substitution Reaction ◽

Metal Ion ◽

Anhydrous Ethanol ◽

Nucleophilic Substitution Reaction ◽

Metal Ion Catalysis

Cation participation in nucleophilic substitution reactions promoted by complexes of polyether ligands with alkali and alkaline-earth metal salts

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29960002505 ◽

1996 ◽

pp. 2505 ◽

Cited By ~ 4

Author(s):

Alessandro Gobbi ◽

Dario Landini ◽

Angelamaria Maia ◽

Michele Penso

Keyword(s):

Nucleophilic Substitution ◽

Alkaline Earth ◽

Earth Metal ◽

Metal Salts ◽

Alkaline Earth Metal ◽

Substitution Reactions ◽

Nucleophilic Substitution Reactions

Nucleophilic Substitution Using Alkali Metal Salts Promoted by PSpentaEG

Synfacts ◽

10.1055/s-0033-1338765 ◽

2013 ◽

Vol 9 (06) ◽

pp. 0684-0684

Keyword(s):

Alkali Metal ◽

Nucleophilic Substitution ◽

Metal Salts ◽

Alkali Metal Salts