Nucleophilic catalysis of hydrolysis of a Schiff base by amines. Intramolecular catalysis of transimination

Tadashi Okuyama; Hiroaki Nagamatsu; Masakazu Kitano; Takayuki Fueno

doi:10.1021/jo00359a025

Nucleophilic catalysis of hydrolysis of a Schiff base by amines. Intramolecular catalysis of transimination

The Journal of Organic Chemistry ◽

10.1021/jo00359a025 ◽

1986 ◽

Vol 51 (9) ◽

pp. 1516-1521 ◽

Cited By ~ 11

Author(s):

Tadashi Okuyama ◽

Hiroaki Nagamatsu ◽

Masakazu Kitano ◽

Takayuki Fueno

Keyword(s):

Schiff Base ◽

Nucleophilic Catalysis ◽

Intramolecular Catalysis ◽

Hydrolysis Of

Intramolecular catalysis of phosphate diester hydrolysis. Nucleophilic catalysis by the neighbouring carboxy-group of the hydrolysis of aryl 2-carboxyphenyl phosphates

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29700001182 ◽

1970 ◽

pp. 1182 ◽

Cited By ~ 8

Author(s):

S. A. Khan ◽

A. J. Kirby ◽

M. Wakselman ◽

D. P. Horning ◽

J. M. Lawlor

Keyword(s):

Carboxy Group ◽

Nucleophilic Catalysis ◽

Intramolecular Catalysis ◽

Phosphate Diester ◽

Hydrolysis Of

Intramolecular catalysis of phosphate triester hydrolysis. Nucleophilic catalysis by the neighbouring carboxy-group of the hydrolysis of diaryl 2-carboxyphenyl phosphates

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29720000911 ◽

1972 ◽

pp. 911 ◽

Cited By ~ 11

Author(s):

R. H. Bromilow ◽

S. A. Khan ◽

A. J. Kirby

Keyword(s):

Carboxy Group ◽

Nucleophilic Catalysis ◽

Intramolecular Catalysis ◽

Hydrolysis Of

Series nucleophilic catalysis in the hydrolysis of 3-acetoxyphthalate. Intramolecular catalysis of ester hydrolysis by the carboxyl group once removed

Journal of the American Chemical Society ◽

10.1021/ja01023a030 ◽

1968 ◽

Vol 90 (21) ◽

pp. 5833-5838 ◽

Cited By ~ 9

Author(s):

A. R. Fersht ◽

A. J. Kirby

Keyword(s):

Ester Hydrolysis ◽

Carboxyl Group ◽

Nucleophilic Catalysis ◽

Intramolecular Catalysis ◽

Hydrolysis Of

ChemInform Abstract: Nucleophilic Catalysis of Hydrolysis of a Schiff Base by Amines.

Chemischer Informationsdienst ◽

10.1002/chin.198650082 ◽

1986 ◽

Vol 17 (50) ◽

Author(s):

T. OKUYAMA ◽

H. NAGAMATSU ◽

M. KITANO ◽

T. FUENO

Keyword(s):

Schiff Base ◽

Nucleophilic Catalysis ◽

Hydrolysis Of

Intramolecular catalysis of phosphate triester hydrolysis. Nucleophilic catalysis by the neighbouring carboxyl group of the hydrolysis of dialkyl 2-carboxyphenyl phosphates

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29710001091 ◽

1971 ◽

pp. 1091 ◽

Cited By ~ 11

Author(s):

R. H. Bromilow ◽

S. A. Khan ◽

A. J. Kirby

Keyword(s):

Carboxyl Group ◽

Nucleophilic Catalysis ◽

Intramolecular Catalysis ◽

Hydrolysis Of

Schiff base equilibria. II. Beryllium complexes of N-n-butylsalicylideneimine and the hydrolysis of the Be2+ ion

Australian Journal of Chemistry ◽

10.1071/ch9650651 ◽

1965 ◽

Vol 18 (5) ◽

pp. 651 ◽

Cited By ~ 12

Author(s):

RW Green ◽

PW Alexander

Keyword(s):

Aqueous Solution ◽

Schiff Base ◽

Complex Formation ◽

Distribution Coefficient ◽

Dilute Aqueous Solution ◽

The Stability ◽

Ph Range ◽

Hydrolysis Of ◽

Beryllium Complexes ◽

Equilibria In Aqueous Solution

The Schiff base, N-n-butylsalicylideneimine, extracts more than 99.8% beryllium into toluene from dilute aqueous solution. The distribution of beryllium has been studied in the pH range 5-13 and is discussed in terms of the several complex equilibria in aqueous solution. The stability constants of the complexes formed between beryllium and the Schiff base are log β1 11.1 and log β2 20.4, and the distribution coefficient of the bis complex is 550. Over most of the pH range, hydrolysis of the Be2+ ion competes with complex formation and provides a means of measuring the hydrolysis constants. They are for the reactions: Be(H2O)42+ ↔ 2H+ + Be(H2O)2(OH)2, log*β2 - 13.65; Be(H2O)42+ ↔ 3H+ + Be(H2O)(OH)3-, log*β3 -24.11.

Imidazole Catalysis. VI.1The Intramolecular Nucleophilic Catalysis of the Hydrolysis of an Acyl Thiol. The Hydrolysis of n-Propyl γ-(4-Imidazolyl)-thiolbutyrate

Journal of the American Chemical Society ◽

10.1021/ja01529a048 ◽

1959 ◽

Vol 81 (20) ◽

pp. 5444-5449 ◽

Cited By ~ 30

Author(s):

Thomas C. Bruice

Keyword(s):

Nucleophilic Catalysis ◽

Hydrolysis Of ◽

Imidazole Catalysis

Catalytic hydrolysis of carboxylic acid esters by Cu(II) and Zn(II) complexes containing a tetracoordinate macrocyclic Schiff base ligand in Brij35 micellar solution

Journal of Molecular Catalysis A Chemical ◽

10.1016/j.molcata.2003.09.004 ◽

2004 ◽

Vol 210 (1-2) ◽

pp. 23-29 ◽

Cited By ~ 33

Author(s):

Xingming Kou ◽

Siqing Cheng ◽

Juan Du ◽

Xiaoqi Yu ◽

Xiancheng Zeng

Keyword(s):

Schiff Base ◽

Carboxylic Acid ◽

Schiff Base Ligand ◽

Micellar Solution ◽

Catalytic Hydrolysis ◽

Hydrolysis Of ◽

Macrocyclic Schiff Base ◽

Acid Esters

A Selective Colorimetric and Fluorescent Chemodosimeter for Fe(III) Ion Based on Hydrolysis of Schiff Base

Journal of the Chinese Chemical Society ◽

10.1002/jccs.201400394 ◽

2015 ◽

Vol 62 (4) ◽

pp. 316-320 ◽

Cited By ~ 6

Author(s):

Haw-Tyng Tsai ◽

Yeshwant Ramchandra Bhorge ◽

Albert J. Pape ◽

Sudhakar Narasimha Janaki ◽

Yao-Pin Yen

Keyword(s):

Schiff Base ◽

Fluorescent Chemodosimeter ◽

Hydrolysis Of

ChemInform Abstract: Intramolecular Proton-Transfer Catalysis of Nucleophilic Catalysis of Acetal Hydrolysis. The Hydrolysis of 8-Dimethylamino-1-methoxymethoxynaphthalene

ChemInform ◽

10.1002/chin.198946071 ◽

1989 ◽

Vol 20 (46) ◽

Author(s):

A. J. KIRBY ◽

J. M. PERCY

Keyword(s):

Proton Transfer ◽

Intramolecular Proton Transfer ◽

Nucleophilic Catalysis ◽

Hydrolysis Of