Combination of Autohydrolysis and Catalytic Hydrolysis of Biomass for the Production of Hemicellulose Oligosaccharides and Sugars

Three different types of biomass sourced from forestry waste (eucalyptus residues), agricultural waste (wheat straw), and energy crop (miscanthus) were used as starting materials to produce hemicellulosic sugars, furans (furfural and hydroxymethylfurfural), and oligosaccharides. A two-step hybrid process was implemented; biomass was first autohydrolysed without any additive to extract hemicelluloses and dissolve it in water. Then, the hydrolysate was treated with a solid acid catalyst, TiO2-WOx, in order to achieve hydrolysis and produce monomeric sugars and furans. This article investigates the role of the biomass type, autohydrolysis experimental conditions, polymerisation degree and composition of hemicelluloses on the performance of the process coupling autohydrolysis and catalytic hydrolysis. The highest global yields of both oligosaccharides and monomeric sugars were obtained from Eucalyptus (37% and 18%, respectively).

The Kinetics Studies on Hydrolysis of Hemicellulose

The kinetics studies is of great importance for the understanding of the mechanism of hemicellulose pyrolysis and expanding the applications of hemicellulose. In the past years, rapid progress has been paid on the kinetics studies of hemicellulose hydrolysis. In this article, we first introduced the hydrolysis of hemicelluloses via various strategies such as autohydrolysis, dilute acid hydrolysis, catalytic hydrolysis, and enzymatic hydrolysis. Then, the history of kinetic models during hemicellulose hydrolysis was summarized. Special attention was paid to the oligosaccharides as intermediates or substrates, acid as catalyst, and thermogravimetric as analyzer method during the hemicellulose hydrolysis. Furthermore, the problems and suggestions of kinetic models during hemicellulose hydrolysis was provided. It expected that this article will favor the understanding of the mechanism of hemicellulose pyrolysis.