Novel synthesis of .alpha.,.beta.-unsaturated ketones by the palladium-catalyzed arylation of ketenes with aroyl chlorides or the decarbonylative cross-condensation of acyl halides

Takeaki Mitsudo; Mamoru Kadokura; Yoshihisa Watanabe

doi:10.1021/jo00391a002

Novel synthesis of .alpha.,.beta.-unsaturated ketones by the palladium-catalyzed arylation of ketenes with aroyl chlorides or the decarbonylative cross-condensation of acyl halides

The Journal of Organic Chemistry ◽

10.1021/jo00391a002 ◽

1987 ◽

Vol 52 (15) ◽

pp. 3186-3192 ◽

Cited By ~ 27

Author(s):

Takeaki Mitsudo ◽

Mamoru Kadokura ◽

Yoshihisa Watanabe

Keyword(s):

Unsaturated Ketones ◽

Novel Synthesis ◽

Palladium Catalyzed ◽

Alpha Beta ◽

Acyl Halides

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ChemInform Abstract: Novel Synthesis of α,β-Unsaturated Ketones by the Palladium-Catalyzed Arylation of Ketenes with Aroyl Chlorides or the Decarbonylative Cross- Condensation of Acyl Halides.

ChemInform ◽

10.1002/chin.198802162 ◽

1988 ◽

Vol 19 (2) ◽

Author(s):

T. MITSUDO ◽

M. KADOKURA ◽

Y. WATANABE

Keyword(s):

Unsaturated Ketones ◽

Novel Synthesis ◽

Palladium Catalyzed ◽

Acyl Halides

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Palladium-catalyzed decarboxylation-dehydrogenation of allyl .beta.-oxo carboxylates and allyl enol carbonates as a novel synthetic method for .alpha.-substituted .alpha.,.beta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00385a075 ◽

1982 ◽

Vol 104 (21) ◽

pp. 5844-5846 ◽

Cited By ~ 82

Author(s):

Isao Shimizu ◽

Jiro Tsuji

Keyword(s):

Synthetic Method ◽

Unsaturated Ketones ◽

Palladium Catalyzed ◽

Alpha Beta

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Palladium-catalyzed asymmetric 1,4-disilylation of .alpha.,.beta.-unsaturated ketones: catalytic asymmetric synthesis of .beta.-hydroxy ketones

Journal of the American Chemical Society ◽

10.1021/ja00224a057 ◽

1988 ◽

Vol 110 (16) ◽

pp. 5579-5581 ◽

Cited By ~ 92

Author(s):

Tamio. Hayashi ◽

Yonetatsu. Matsumoto ◽

Yoshihiko. Ito

Keyword(s):

Asymmetric Synthesis ◽

Unsaturated Ketones ◽

Catalytic Asymmetric Synthesis ◽

Hydroxy Ketones ◽

Palladium Catalyzed ◽

Alpha Beta ◽

Catalytic Asymmetric

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Palladium-catalyzed conjugate addition type reaction of (2-hydroxyaryl)mercury chlorides with .alpha.,.beta.-unsaturated ketones in a two-phase system. A new synthesis of 2-chromanols and 2-chromenes

The Journal of Organic Chemistry ◽

10.1021/jo00136a036 ◽

1982 ◽

Vol 47 (15) ◽

pp. 2995-2999 ◽

Cited By ~ 18

Author(s):

S. Cacchi ◽

D. Misiti ◽

G. Palmieri

Keyword(s):

Conjugate Addition ◽

Phase System ◽

Two Phase ◽

Unsaturated Ketones ◽

Type Reaction ◽

System A ◽

New Synthesis ◽

Palladium Catalyzed ◽

Alpha Beta

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Ruthenium-catalyzed allylation of primary alcohols by allylic acetates: a novel synthesis of .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo00002a003 ◽

1991 ◽

Vol 56 (2) ◽

pp. 487-489 ◽

Cited By ~ 28

Author(s):

Teruyuki Kondo ◽

Takeshi Mukai ◽

Yoshihisa Watanabe

Keyword(s):

Primary Alcohols ◽

Unsaturated Ketones ◽

Novel Synthesis ◽

Alpha Beta

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Palladium-catalyzed conjugate addition reaction of aryl iodides with .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo00171a016 ◽

1983 ◽

Vol 48 (23) ◽

pp. 4236-4240 ◽

Cited By ~ 95

Author(s):

S. Cacchi ◽

A. Arcadi

Keyword(s):

Addition Reaction ◽

Conjugate Addition ◽

Unsaturated Ketones ◽

Aryl Iodides ◽

Palladium Catalyzed ◽

Alpha Beta

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Palladium-Catalyzed Three-Component Coupling Reaction of Benzyl Chlorides, Allyltributylstannane, and Carbon Monoxide: Efficient Synthesis of α,β-Unsaturated Ketones

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) ◽

10.3724/sp.j.1088.2012.10930 ◽

2013 ◽

Vol 33 (3) ◽

pp. 523-529

Author(s):

Xin ZHANG ◽

Xiujuan FENG ◽

Hesong LIU ◽

Yuhu QIN ◽

Yao DAI

Keyword(s):

Carbon Monoxide ◽

Coupling Reaction ◽

Efficient Synthesis ◽

Unsaturated Ketones ◽

Benzyl Chlorides ◽

Palladium Catalyzed ◽

Three Component Coupling

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Novel Synthesis of Indoles via Palladium-Catalyzed Reductive N-Heterocyclization ofo-Nitrostyrene Derivatives

Chemistry Letters ◽

10.1246/cl.1992.769 ◽

1992 ◽

Vol 21 (5) ◽

pp. 769-772 ◽

Cited By ~ 45

Author(s):

Motohiro Akazome ◽

Teruyuki Kondo ◽

Yoshihisa Watanabe

Keyword(s):

Novel Synthesis ◽

Palladium Catalyzed

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Base-catalyzed intermolecular condensation of .alpha.,.beta.-unsaturated ketones. Condensation of benzaldehyde with 2-butanone to diketones 3,5-diphenyl-2-methyl-4-propionylcyclohexan-1-one and 4-(2-benzalpropionyl)-3,5-diphenyl-2-methylcyclohexan-1-one

The Journal of Organic Chemistry ◽

10.1021/jo01286a028 ◽

1967 ◽

Vol 32 (11) ◽

pp. 3407-3411 ◽

Cited By ~ 5

Author(s):

Arnold T. Nielsen ◽

Henry Dubin ◽

Kerry Hise

Keyword(s):

Unsaturated Ketones ◽

Alpha Beta

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Tandem conjugate addition. Aldol reactions employing 9-(phenylseleno)-9-borabicyclononane: a novel method for effecting formal aldol condensations at the .alpha.-carbon of .alpha.,.beta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo00205a048 ◽

1985 ◽

Vol 50 (5) ◽

pp. 730-732 ◽

Cited By ~ 30

Author(s):

William R. Leonard ◽

Tom Livinghouse

Keyword(s):

Conjugate Addition ◽

Aldol Reactions ◽

Unsaturated Ketones ◽

Novel Method ◽

Alpha Beta ◽

Alpha Carbon

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