Electronic and Steric Effects on the Mechanism of the Inverse Electron Demand Diels−Alder Reaction of 2-Aminopyrroles with 1,3,5-Triazines: Identification of Five Intermediates by1H,13C,15N, and19F NMR Spectroscopy

2009 ◽  
Vol 74 (1) ◽  
pp. 319-328 ◽  
Author(s):  
Michael De Rosa ◽  
David Arnold
Keyword(s):  
Nmr Spectroscopy ◽  
Alder Reaction ◽  
Diels Alder ◽  
Steric Effects ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand ◽  
Electronic And Steric Effects

Synthesis of Medium-Sized Carbocycles via a Bidentate Lewis Acid-Catalyzed Inverse Electron-Demand Diels–Alder Reaction Followed by Photoinduced Ring-Opening

2021 ◽  
Author(s):  
Julia Ruhl ◽  
Sebastian Ahles ◽  
Marcel A. Strauss ◽  
Christopher M. Leonhardt ◽  
Hermann A. Wegner
Keyword(s):  
Lewis Acid ◽  
Ring Opening ◽  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Acid Catalyzed ◽  
Electron Demand

PPh3-catalyzed synthesis of dicyano-2-methylenebut-3-enoates as efficient dienes in catalytic asymmetric inverse-electron-demand Diels–Alder reaction

2011 ◽  
Vol 47 (29) ◽  
pp. 8289 ◽  
Author(s):  
Xianxing Jiang ◽  
Dan Fu ◽  
Xiaomei Shi ◽  
Shoulei Wang ◽  
Rui Wang
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Catalytic Asymmetric ◽  
Electron Demand

Highly Enantioselective Catalytic Hetero-Diels-Alder Reaction with Inverse Electron Demand

1998 ◽  
Vol 37 (17) ◽  
pp. 2404-2406 ◽  
Author(s):  
Jacob Thorhauge ◽  
Mogens Johannsen ◽  
Karl Anker Jørgensen
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

Single wall carbon nanotube (SWCNT)–gold nanorod (AuNR) conjugates via thermally-mild reaction conditions

2017 ◽  
Vol 41 (21) ◽  
pp. 12392-12396 ◽  
Author(s):  
Siting Ni ◽  
Jun Zhu ◽  
Mohamed Amine Mezour ◽  
R. Bruce Lennox
Keyword(s):  
Carbon Nanotube ◽  
Covalent Binding ◽  
Alder Reaction ◽  
Diels Alder ◽  
Gold Nanorod ◽  
Reaction Conditions ◽  
Single Wall Carbon ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

A thermally-mild method for covalent binding of SWCNTs to AuNRs, based on an inverse-electron-demand Diels–Alder reaction, is established and discussed.

scholarly journals Front Cover Picture: Stereoselective Synthesis of Hydropyrano[3,2-b]indolesviaOrganocatalytic Asymmetric Inverse-Electron-Demand Oxa-Diels-Alder Reaction (Adv. Synth. Catal. 18/2016)

2016 ◽  
Vol 358 (18) ◽  
pp. 2861-2861
Author(s):  
Lei Yang ◽  
Wei Huang ◽  
Xiang-Hong He ◽  
Ming-Cheng Yang ◽  
Xiang Li ◽  
...  
Keyword(s):  
Stereoselective Synthesis ◽  
Alder Reaction ◽  
Diels Alder ◽  
Front Cover ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand

Total syntheses of ericifolione and analogues via a biomimetic inverse-electron-demand Diels-Alder reaction

2021 ◽  
Author(s):  
Tingting Zhou ◽  
Anquan Zheng ◽  
Luqiong Huo ◽  
Changgeng Li ◽  
Haibo Tan ◽  
...  
Keyword(s):  
Sodium Acetate ◽  
Alder Reaction ◽  
Diels Alder ◽  
Total Syntheses ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Sterically Hindered ◽  
Electron Demand

Driven by bioinspiration and appreciation of the structure of ericifolione, a biomimetic tautomerization/intermolecular inverse-electron-demand hetero Diels-Alder reaction cascade sequence promoted by sodium acetate to rapidly construct sterically hindered dihydropyran scaffolds...

Synthesis of 6H-Dibenzo[b,d]pyran-6-ones Using the Inverse Electron Demand Diels–Alder Reaction

2011 ◽  
Vol 76 (21) ◽  
pp. 9015-9030 ◽  
Author(s):  
Ian R. Pottie ◽  
Penchal Reddy Nandaluru ◽  
Wendy L. Benoit ◽  
David O. Miller ◽  
Louise N. Dawe ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Diels Alder Reaction ◽  
Electron Demand
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