A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds

1997 ◽  
Vol 62 (20) ◽  
pp. 6974-6977 ◽  
Author(s):  
Antonella De Mico ◽  
Roberto Margarita ◽  
Luca Parlanti ◽  
Andrea Vescovi ◽  
Giovanni Piancatelli
Keyword(s):  
Carbonyl Compounds ◽  
Hypervalent Iodine ◽  
Oxidation Of Alcohols ◽  
Mediated Oxidation

Hypervalent iodine-mediated oxidation of alcohols

2009 ◽  
pp. 2086 ◽  
Author(s):  
Muhammet Uyanik ◽  
Kazuaki Ishihara
Keyword(s):  
Hypervalent Iodine ◽  
Oxidation Of Alcohols ◽  
Mediated Oxidation

scholarly journals Hypervalent iodine/TEMPO-mediated oxidation in flow systems: a fast and efficient protocol for alcohol oxidation

2013 ◽  
Vol 9 ◽  
pp. 1437-1442 ◽  
Author(s):  
Nida Ambreen ◽  
Ravi Kumar ◽  
Thomas Wirth
Keyword(s):  
Carbonyl Compounds ◽  
Reaction Times ◽  
Alcohol Oxidation ◽  
Hypervalent Iodine ◽  
Allylic Alcohols ◽  
Flow Systems ◽  
Microreactor Technology ◽  
Mediated Oxidation

Hypervalent iodine(III)/TEMPO-mediated oxidation of various aliphatic, aromatic and allylic alcohols to their corresponding carbonyl compounds was successfully achieved by using microreactor technology. This method can be used as an alternative for the oxidation of various alcohols achieving excellent yields and selectivities in significantly shortened reaction times.

scholarly journals Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways

RSC Advances ◽  
2018 ◽  
Vol 8 (56) ◽  
pp. 32055-32062 ◽  
Author(s):  
Ajay H. Bansode ◽  
Gurunath Suryavanshi
Keyword(s):  
Carbonyl Compounds ◽  
Reaction Pathways ◽  
Secondary Amines ◽  
Hypervalent Iodine ◽  
Metal Free ◽  
Highly Efficient ◽  
Mechanistic Insight ◽  
Primary And Secondary Amines ◽  
Mediated Oxidation ◽  
Insight Into

A highly efficient, metal free rapid protocol studied mechanistically the oxidation of primary and secondary amines to their corresponding carbonyl compounds using PhI(OAc)2and catalytic TEMPO to provide diverse products in excellent yields.

Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds using N-hydroxyphthalimide (NHPI) and m-chloroperbenzoic acid

2010 ◽  
Vol 88 (4) ◽  
pp. 362-366 ◽  
Author(s):  
Chenjie Zhu ◽  
Lei Ji ◽  
Qian Zhang ◽  
Yunyang Wei
Keyword(s):  
Carbonyl Compounds ◽  
Room Temperature ◽  
Mixed Solvent ◽  
Catalytic Amount ◽  
Hypervalent Iodine ◽  
Mild Oxidation ◽  
Oxidation Of Alcohols

An efficient, facile, and mild oxidation of alcohols to the corresponding carbonyl compounds with m-chloroperbenzoic acid (mCPBA) and N-hydroxyphthalimide (NHPI) in the presence of a catalytic amount of iodobenzene was reported. The oxidation proceeded in mixed solvent at room temperature to afford carbonyl compounds in excellent yields. A possible mechanism for the oxidation was proposed.

ChemInform Abstract: Hypervalent Iodine-Mediated Oxidation of Alcohols

ChemInform ◽  
2009 ◽  
Vol 40 (32) ◽  
Author(s):  
Muhammet Uyanik ◽  
Kazuaki Ishihara
Keyword(s):  
Hypervalent Iodine ◽  
Oxidation Of Alcohols ◽  
Mediated Oxidation
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