scholarly journals Metal-free hypervalent iodine/TEMPO mediated oxidation of amines and mechanistic insight into the reaction pathways

RSC Advances ◽  
2018 ◽  
Vol 8 (56) ◽  
pp. 32055-32062 ◽  
Author(s):  
Ajay H. Bansode ◽  
Gurunath Suryavanshi
Keyword(s):  
Carbonyl Compounds ◽  
Reaction Pathways ◽  
Secondary Amines ◽  
Hypervalent Iodine ◽  
Metal Free ◽  
Highly Efficient ◽  
Mechanistic Insight ◽  
Primary And Secondary Amines ◽  
Mediated Oxidation ◽  
Insight Into

A highly efficient, metal free rapid protocol studied mechanistically the oxidation of primary and secondary amines to their corresponding carbonyl compounds using PhI(OAc)2and catalytic TEMPO to provide diverse products in excellent yields.

scholarly journals Hypervalent iodine/TEMPO-mediated oxidation in flow systems: a fast and efficient protocol for alcohol oxidation

2013 ◽  
Vol 9 ◽  
pp. 1437-1442 ◽  
Author(s):  
Nida Ambreen ◽  
Ravi Kumar ◽  
Thomas Wirth
Keyword(s):  
Carbonyl Compounds ◽  
Reaction Times ◽  
Alcohol Oxidation ◽  
Hypervalent Iodine ◽  
Allylic Alcohols ◽  
Flow Systems ◽  
Microreactor Technology ◽  
Mediated Oxidation

Hypervalent iodine(III)/TEMPO-mediated oxidation of various aliphatic, aromatic and allylic alcohols to their corresponding carbonyl compounds was successfully achieved by using microreactor technology. This method can be used as an alternative for the oxidation of various alcohols achieving excellent yields and selectivities in significantly shortened reaction times.

A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds

1997 ◽  
Vol 62 (20) ◽  
pp. 6974-6977 ◽  
Author(s):  
Antonella De Mico ◽  
Roberto Margarita ◽  
Luca Parlanti ◽  
Andrea Vescovi ◽  
Giovanni Piancatelli
Keyword(s):  
Carbonyl Compounds ◽  
Hypervalent Iodine ◽  
Oxidation Of Alcohols ◽  
Mediated Oxidation
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