Spectroscopically Probing Microscopic Solvent Properties of Room-Temperature Ionic Liquids with the Addition of Carbon Dioxide

2003 ◽  
Vol 107 (19) ◽  
pp. 3995-4000 ◽  
Author(s):  
Jie Lu ◽  
Charles L. Liotta ◽  
Charles A. Eckert
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Solvent Properties

scholarly journals Solvation dynamics of coumarin 153 in mixtures of carbon dioxide and room temperature ionic liquids

2011 ◽  
Vol 513 (1-3) ◽  
pp. 53-58 ◽  
Author(s):  
Yoshifumi Kimura ◽  
Akira Kobayashi ◽  
Masashi Demizu ◽  
Masahide Terazima
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Solvation Dynamics ◽  
Coumarin 153

Comparison of Polarities of Room-Temperature Ionic Liquids Using FT-IR Spectroscopic Probes

2005 ◽  
Vol 58 (5) ◽  
pp. 327 ◽  
Author(s):  
Guo-hong Tao ◽  
Ming Zou ◽  
Xiao-hua Wang ◽  
Zhi-yu Chen ◽  
David G. Evans ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Ionic Liquids ◽  
Ftir Spectroscopy ◽  
Room Temperature ◽  
General Type ◽  
Room Temperature Ionic Liquids ◽  
Spectroscopic Probes ◽  
Ft Ir ◽  
Ir Spectroscopic ◽  
Solvent Properties

The solvent properties, especially the polarity, of room-temperature ionic liquids (RTILs) of the general type [Cnmim]X, where [Cnmim] is the 1-CnH2n+1-3-methylimidazolium cation and X is [BF4]−, [PF6]−, [NO3]−, [SCN]−, or [NTf2]− (Tf = CF3SO2), have been investigated using Fourier-transform infrared (FTIR) spectroscopy. Comparing the experimental shifts in the νC=O stretching frequencies of acetone and N,N-dimethylformamide (DMF) as probe molecules suggests that the polarities of most common RTILs are between that of DMF and methanol. A more sensitive probe, Fe(CO)5, can distinguish small polarity differences between RTILs with similar structures. The effects of varying the structure of RTILs by introducing functional groups and different anions on their polarity are also compared.

Optical Carbon Dioxide Sensors Based on Silicone-Encapsulated Room-Temperature Ionic Liquids

2007 ◽  
Vol 19 (25) ◽  
pp. 6187-6194 ◽  
Author(s):  
Sergey M. Borisov ◽  
Magdalena Ch. Waldhier ◽  
Ingo Klimant ◽  
Otto S. Wolfbeis
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Carbon Dioxide Sensors
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