scholarly journals A Distributed Activation Energy Model of Thermodynamically Inhibited Nucleation and Growth Reactions and Its Application to the β−δ Phase Transition of HMX

2004 ◽  
Vol 108 (50) ◽  
pp. 19432-19441 ◽  
Author(s):  
Alan K. Burnham ◽  
Randall K. Weese ◽  
Brandon L. Weeks
ACS Omega ◽  
2021 ◽  
Vol 6 (17) ◽  
pp. 11436-11446
Author(s):  
Yui Numazawa ◽  
Yuki Hara ◽  
Yoshiya Matsukawa ◽  
Yohsuke Matsushita ◽  
Hideyuki Aoki ◽  
...  

2015 ◽  
Vol 121 (3) ◽  
pp. 1403-1410 ◽  
Author(s):  
Benedetta de Caprariis ◽  
Maria Laura Santarelli ◽  
Marco Scarsella ◽  
Carlos Herce ◽  
Nicola Verdone ◽  
...  

2016 ◽  
Vol 27 (3) ◽  
pp. 67-83 ◽  
Author(s):  
Bemgba Bevan Nyakuma ◽  
◽  
Arshad Ahmad ◽  
Anwar Johari ◽  
Tuan Amran Tuan Abdullah ◽  
...  

2013 ◽  
Vol 641-642 ◽  
pp. 144-147 ◽  
Author(s):  
Ming Hua Chen ◽  
Tao Zhang ◽  
Wen Ping Chang ◽  
Xiao Biao Jia

The thermal decomposition kinetics of RDX at different rates was studied by thermogravimetric analyzer(TG) and the activation energy of RDX was calculated by distributed activation energy model. It is shown that the thermal decomposition processes of RDX were divided into three stages according to the TG curves, they are molten stage, thermal decomposition stage and eng stage. The activation energies of RDX are all between 124.34 and 181.48KJ•mol-1 in the thermal decomposition stage of non-monotonously increasing. The activation energy of RDX is 139.98 KJ•mol-1 in the molten stage, and the thermal decomposition stage is167.24KJ•mol-1.


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