Random Activation Energy Model and Disordered Kinetics, from Static to Dynamic Disorder†

2005 ◽  
Vol 109 (45) ◽  
pp. 21241-21257 ◽  
Author(s):  
Marcel Ovidiu Vlad ◽  
Gianfranco Cerofolini ◽  
Peter Oefner ◽  
John Ross

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Vol 121 (3) ◽  
pp. 1403-1410 ◽  
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Benedetta de Caprariis ◽  
Maria Laura Santarelli ◽  
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Vol 118 ◽  
pp. 223-230 ◽  
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Elke Goos ◽  
Jorge Arrieta-Sanagustín ◽  
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2013 ◽  
Vol 641-642 ◽  
pp. 144-147 ◽  
Author(s):  
Ming Hua Chen ◽  
Tao Zhang ◽  
Wen Ping Chang ◽  
Xiao Biao Jia

The thermal decomposition kinetics of RDX at different rates was studied by thermogravimetric analyzer(TG) and the activation energy of RDX was calculated by distributed activation energy model. It is shown that the thermal decomposition processes of RDX were divided into three stages according to the TG curves, they are molten stage, thermal decomposition stage and eng stage. The activation energies of RDX are all between 124.34 and 181.48KJ•mol-1 in the thermal decomposition stage of non-monotonously increasing. The activation energy of RDX is 139.98 KJ•mol-1 in the molten stage, and the thermal decomposition stage is167.24KJ•mol-1.



2019 ◽  
Vol 294 ◽  
pp. 122099 ◽  
Author(s):  
Inamullah Mian ◽  
Xian Li ◽  
Yiming Jian ◽  
Omar D. Dacres ◽  
Mei Zhong ◽  
...  


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