Self-Assembly of Well-Defined Poly(3-hexylthiophene) Nanostructures toward the Structure–Property Relationship Determination of Polymer Solar Cells

2012 ◽  
Vol 116 (45) ◽  
pp. 23858-23863 ◽  
Author(s):  
Zai Yu ◽  
Jin Fang ◽  
Han Yan ◽  
Yajie Zhang ◽  
Kun Lu ◽  
...  
2014 ◽  
Vol 16 (3) ◽  
pp. 1067-1077 ◽  
Author(s):  
S. Brück ◽  
C. Krause ◽  
R. Turrisi ◽  
L. Beverina ◽  
S. Wilken ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 51807-51815 ◽  
Author(s):  
Ashok Keerthi ◽  
Ming Hui Chua ◽  
Thuang Yuan Timothy Chan ◽  
Yeru Liu ◽  
Qing Wang ◽  
...  

Multi-donor incorporated organic dyes were designed and synthesized and their structure–property relationship was investigated in dye-sensitized solar cells (DSCs).


2017 ◽  
Vol 50 (5) ◽  
pp. 1289-1298
Author(s):  
Andrew J. Mulderig ◽  
Yan Jin ◽  
Fei Yu ◽  
Jong Keum ◽  
Kunlun Hong ◽  
...  

This study investigates the structure of films spin-coated from blends of the semiconducting polymers poly(3-hexylthiophene-2,5-diyl) (P3HT) and poly{2,6-[4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene]-alt-4,7(2,1,3-benzothiadiazole)} (PCPDTBT). Such blends are of potential use in all-polymer solar cells in which both the acceptor and the donor material generate excitons to contribute to the photocurrent. Prompted by threefold performance gains seen in polymer/fullerene and polymer blend solar cells upon addition of pristine graphene, devices are prepared from P3HT/PCPDTBT blends both with and without graphene. This report focuses on the morphology of the active layer since this is of critical importance in determining performance. Small-angle neutron scattering (SANS) is utilized to study this polymer blend with deuterated P3HT to provide contrast and permit the investigation of buried structure in neat and graphene-doped films. SANS reveals the presence of P3HT crystallites dispersed in an amorphous blend matrix of P3HT and PCPDTBT. The crystallites are approximately disc shaped and do not show any evidence of higher-order structure or aggregation. While the structure of the films does not change with the addition of graphene, there is a perceptible effect on the electronic properties and energy conversion efficiency in solar cells made from such films. Determination of the active layer morphology yields crucial insight into structure–property relationships in organic photovoltaic devices.


2019 ◽  
Vol 21 (20) ◽  
pp. 10488-10496 ◽  
Author(s):  
Ping Li ◽  
Zhixiang Wang ◽  
Houyu Zhang

Quantum calculations on rigidified and expanded NP-based dyes were carried out to establish the structure–property relationship.


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