Anion-Dependence of Fast Relaxation Component in Na-, K-Halide Solutions at Low Concentrations Measured by High-Resolution Microwave Dielectric Spectroscopy

2013 ◽  
Vol 117 (23) ◽  
pp. 4851-4862 ◽  
Author(s):  
George Mogami ◽  
Takashi Miyazaki ◽  
Tetsuichi Wazawa ◽  
Nobuyuki Matubayasi ◽  
Makoto Suzuki

2014 ◽  
Vol 86 (2) ◽  
pp. 181-189 ◽  
Author(s):  
Makoto Suzuki

Abstract Experimental observation by high-resolution microwave dielectric spectroscopy of hydration properties of alkali halide ions, adenosine phosphate ions, and F-actin revealed the existence of hypermobile water (HMW) molecules around those solutes. To understand the molecular process of HMW, two theoretical approaches are reviewed here. One is based on a statistical mechanical approach to analyze the rotational freedom of water molecules around a charged particle. Another approach reports direct calculation of dielectric relaxation process of water molecules around an ion. Experimentally observed HMW molecules are theoretically explained with the significance of multi-correlations among an ion and water molecules.



2002 ◽  
Vol 82 (1) ◽  
pp. 418-425 ◽  
Author(s):  
Takashi Kamei ◽  
Motohisa Oobatake ◽  
Makoto Suzuki


2000 ◽  
Vol 40 (supplement) ◽  
pp. S176
Author(s):  
M. Suzuki ◽  
K. Yokoyama ◽  
T. Kamei ◽  
H. Minami




Author(s):  
J M Matey ◽  
Adrián López-Fernández ◽  
Carmen García-Ruiz ◽  
Gemma Montalvo ◽  
M D Moreno ◽  
...  

Abstract The analysis of drugs of abuse in hair and other biological matrices of forensic interest requires great selectivity and sensitivity. This is done traditionally through target analysis, with one or more analytical methods, or with different and specific preanalytical phases, and complex procedures performed by the toxicological laboratories, and there is no exception with ketamine-like compounds, such as methoxetamine, a new psychoactive substance whose use has increased in the last decades, and continues to grow quickly year by year. More validated methods of analysis are needed to detect these substances in low concentrations selectively. Reanalyzing the samples of a former case of a polydrug consumer accused of a crime against public health in Spain, five metabolites of methoxetamine (normethoxetamine, O-desmethylmethoxetamine, dehydromethoxetamine, dihydronormethoxetamine and hydroxynormethoxetamine) were tentatively detected using a high-resolution technique, i.e., liquid chromatography coupled to high-resolution mass spectrometry (LC–HR-MS-MS). The highest analytical selectivity of LC–HR-MS-MS method together a universal and simpler pretreatment stages has demonstrated to allow faster analysis and more sensitivity than the one performed traditionally at the INTCF laboratories, which was gas chromatography coupled to mass spectrometry.



Author(s):  
Francois Artis ◽  
David Dubuc ◽  
Jean-Jacques Fournie ◽  
Mary Poupot ◽  
Katia Grenier


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