Kinetics of Cap Separation in Nitroxide-Regulated “Living” Free Radical Polymerization:  Application of a Novel Methodology Involving a Prefluorescent Nitroxide Switch

2001 ◽  
Vol 34 (18) ◽  
pp. 6184-6187 ◽  
Author(s):  
Olga García Ballesteros ◽  
Luca Maretti ◽  
Roberto Sastre ◽  
J. C. Scaiano
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

The Kinetics of Free-Radical Polymerization: Fundamental Aspects

2002 ◽  
Vol 55 (7) ◽  
pp. 399 ◽  
Author(s):  
G. T. Russell
Keyword(s):  
Molecular Weight ◽  
Steady State ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Free Radical Polymerization ◽  
Length Dependence ◽  
Model Independent ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed.

Kinetics of Controlled ‘Living’ Free Radical Polymerization: I. Ideal Case

1999 ◽  
Vol 7 (2) ◽  
pp. 283-300 ◽  
Author(s):  
An-Chang Shi ◽  
Michael K. Georges ◽  
Hadi K. Mahabadi
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Ideal Case ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Probing the reaction kinetics of vinyl acetate free radical polymerization via living free radical polymerization (MADIX)

Polymer ◽  
2006 ◽  
Vol 47 (4) ◽  
pp. 999-1010 ◽  
Author(s):  
Alexander Theis ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Free Radical ◽  
Reaction Kinetics ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Kinetics of “living” free radical polymerization

1999 ◽  
Vol 54 (15-16) ◽  
pp. 3225-3231 ◽  
Author(s):  
Alessandro Butté ◽  
Giuseppe Storti ◽  
Massimo Morbidelli
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Photochemical synthesis of TEMPO-capped initiators for “living” free radical polymerization

1996 ◽  
Vol 37 (28) ◽  
pp. 4919-4922 ◽  
Author(s):  
Terrence J. Connolly ◽  
M.V. Baldoví ◽  
N. Mohtat ◽  
J.C. Scaiano
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Photochemical Synthesis ◽  
Living Free Radical Polymerization

Synthesis of Poly(olefin) Graft Copolymers by a Combination of Metallocene and “Living” Free Radical Polymerization Techniques

1998 ◽  
Vol 31 (13) ◽  
pp. 4396-4398 ◽  
Author(s):  
Udo M. Stehling ◽  
Eva E. Malmström ◽  
Robert M. Waymouth ◽  
Craig J. Hawker
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Graft Copolymers ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization
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