Propagation Kinetics of Para-Substituted Styrenes:  A Test of the Applicability of the Hammett Relationship to Free-Radical Polymerization

1999 ◽  
Vol 32 (13) ◽  
pp. 4290-4298 ◽  
Author(s):  
Michelle L. Coote ◽  
Thomas P. Davis
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Kinetics Of ◽  
Hammett Relationship

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Non-steady-state model for kinetics of free radical polymerization, 2. Redox initiation

1992 ◽  
Vol 28 (2) ◽  
pp. 115-121 ◽  
Author(s):  
Deyue Yan ◽  
Jianming Lin ◽  
Cuiming Yuan ◽  
Jing Feng
Keyword(s):  
Steady State ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
State Model ◽  
Redox Initiation ◽  
Steady State Model ◽  
Kinetics Of

The Kinetics of Free-Radical Polymerization: Fundamental Aspects

2002 ◽  
Vol 55 (7) ◽  
pp. 399 ◽  
Author(s):  
G. T. Russell
Keyword(s):  
Molecular Weight ◽  
Steady State ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Free Radical Polymerization ◽  
Length Dependence ◽  
Model Independent ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed.

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