Reversible Addition−Fragmentation Chain Transfer Polymerization:  End Group Modification for Functionalized Polymers and Chain Transfer Agent Recovery

2005 ◽  
Vol 38 (6) ◽  
pp. 2033-2036 ◽  
Author(s):  
Sébastien Perrier ◽  
Pittaya Takolpuckdee ◽  
Craig A. Mars
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Functionalized Polymers ◽  
Reversible Addition ◽  
Group Modification ◽  
End Group Modification ◽  
Chain Transfer Polymerization ◽  
End Group

scholarly journals Synthesis of aminated polystyrene and its self-assembly with nanoparticles at oil/water interface

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 317-327
Author(s):  
Chenliang Shi ◽  
Ling Lin ◽  
Yukun Yang ◽  
Wenjia Luo ◽  
Maoqing Deng ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Self Assembly ◽  
Carbon Dots ◽  
Chain Transfer ◽  
Functionalized Polymers ◽  
Amino Groups ◽  
One Dimensional ◽  
Reversible Addition ◽  
Oil Water ◽  
Chain Transfer Polymerization

AbstractThe influence of density of amino groups, nanoparticles dimension and pH on the interaction between end-functionalized polymers and nanoparticles was extensively investigated in this study. PS–NH2 and H2N–PS–NH2 were prepared using reversible addition–fragmentation chain transfer polymerization and atom transfer radical polymerization. Zero-dimensional carbon dots with sulfonate groups, one-dimensional cellulose nanocrystals with sulfate groups and two-dimensional graphene with sulfonate groups in the aqueous phase were added into the toluene phase containing the aminated PS. The results indicate that aminated PS exhibited the strongest interfacial activity after compounding with sulfonated nanoparticles at a pH of 3. PS ended with two amino groups performed better in reducing the water/toluene interfacial tension than PS ended with only one amino group. The dimension of sulfonated nanoparticles also contributed significantly to the reduction in the water/toluene interfacial tension. The minimal interfacial tension was 4.49 mN/m after compounding PS–NH2 with sulfonated zero-dimensional carbon dots.

scholarly journals Synthesis of bottlebrush polymers via transfer-to and grafting-through approaches using a RAFT chain transfer agent with a ROMP-active Z-group

2015 ◽  
Vol 6 (31) ◽  
pp. 5643-5652 ◽  
Author(s):  
Scott C. Radzinski ◽  
Jeffrey C. Foster ◽  
John B. Matson
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Multiple Strategies ◽  
Reversible Addition ◽  
Grafting Through ◽  
Chain Transfer Polymerization

A novel dithiocarbamate chain transfer agent for reversible addition–fragmentation chain transfer polymerization with a directly polymerizable Z-group was synthesized and used to make bottlebrush polymers via multiple strategies.

Novel Amide-Based Chain Transfer Agent for Reversible Addition Fragmentation Chain Transfer Polymerization

2005 ◽  
Vol 38 (4) ◽  
pp. 1057-1060 ◽  
Author(s):  
Pittaya Takolpuckdee ◽  
Craig A. Mars ◽  
Sébastien Perrier ◽  
Stephen J. Archibald
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

scholarly journals Piezoelectrically Mediated Reversible Addition-Fragmentation Chain Transfer Polymerization

2022 ◽  
Author(s):  
Chengqiang Ding ◽  
Zhengbiao Zhang ◽  
zhao wang
Keyword(s):  
Chain Transfer ◽  
Uv Curing ◽  
Composite Resins ◽  
Chain Extension ◽  
Light Penetration ◽  
Reversible Addition ◽  
Good Potential ◽  
Chain Transfer Polymerization ◽  
Trans Ducer ◽  
End Group

A well-controlled piezoelectrically mediated reversible addition-fragmentation chain transfer polymerization (piezo-RAFT) was carried out under ultrasound agitation with piezoelectric ZnO nanoparticles as the mechano-chemical trans-ducer. The resulting polymer had predictable molecular weight, high end-group fidelity, low dispersity, and capacity for chain extension. This chemistry was further adopted in curing composite resins to circumvent the light penetration limit of UV curing. This work opened a new avenue of piezoelectrically mediated chemistry and showed its good potential in curing applications.

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