Hydrogen-Bond-Directed Formation of Supramolecular Polymers Incorporating Head-to-Tail Oriented Dipolar Merocyanine Dyes

2011 ◽  
Vol 44 (10) ◽  
pp. 3766-3776 ◽  
Author(s):  
Ralf Schmidt ◽  
Matthias Stolte ◽  
Matthias Grüne ◽  
Frank Würthner
Keyword(s):  
Hydrogen Bond ◽  
Supramolecular Polymers ◽  
Merocyanine Dyes

New self-assembled supramolecular polymers formed by self-complementary sextuple hydrogen bond motifs

RSC Advances ◽  
2012 ◽  
Vol 2 (26) ◽  
pp. 9952 ◽  
Author(s):  
Chih-Chia Cheng ◽  
I-Hong Lin ◽  
Ying-Chieh Yen ◽  
Chih-Wei Chu ◽  
Fu-Hsiang Ko ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Supramolecular Polymers ◽  
Self Assembled

scholarly journals Chain stopper engineering for hydrogen bonded supramolecular polymers

2010 ◽  
Vol 6 ◽  
pp. 869-875 ◽  
Author(s):  
Thomas Pinault ◽  
Bruno Andrioletti ◽  
Laurent Bouteiller
Keyword(s):  
Hydrogen Bond ◽  
Molar Mass ◽  
Strong Hydrogen Bond ◽  
Supramolecular Polymers ◽  
Supramolecular Polymer ◽  
Hydrogen Bond Donor ◽  
Linear Chains ◽  
Non Covalent Interactions ◽  
Viscous Solutions ◽  
Covalent Interactions

Supramolecular polymers are linear chains of low molar mass monomers held together by reversible and directional non-covalent interactions, which can form gels or highly viscous solutions if the self-assembled chains are sufficiently long and rigid. The viscosity of these solutions can be controlled by adding monofunctional compounds, which interact with the chain extremities: chain stoppers. We have synthesized new substituted ureas and thioureas and tested them as chain stoppers for a bis-urea based supramolecular polymer. In particular, the bis-thiourea analogue of the bis-urea monomer is shown not to form a supramolecular polymer, but a good chain stopper, because it is a strong hydrogen bond donor and a weak acceptor. Moreover, all substituted ureas tested reduce the viscosity of the supramolecular polymer solutions, but the best chain stopper is obtained when two hydrogen bond acceptors are placed in the same relative position as for the monomer and when no hydrogen bond donor is present.

Hydrogen-Bond-Directed Head-to-Tail Orientation of Dipolar Merocyanine Dyes: A Strategy for the Design of Electrooptical Materials

2006 ◽  
Vol 45 (23) ◽  
pp. 3842-3846 ◽  
Author(s):  
Frank Würthner ◽  
Johann Schmidt ◽  
Matthias Stolte ◽  
Rüdiger Wortmann
Keyword(s):  
Hydrogen Bond ◽  
Merocyanine Dyes

Bio-complementary supramolecular polymers with effective self-healing functionality

RSC Advances ◽  
2015 ◽  
Vol 5 (110) ◽  
pp. 90466-90472 ◽  
Author(s):  
Chih-Chia Cheng ◽  
Feng-Chih Chang ◽  
Shenghong A. Dai ◽  
Yu-Li Lin ◽  
Duu-Jong Lee
Keyword(s):  
Hydrogen Bond ◽  
Supramolecular Polymers ◽  
Self Healing ◽  
Temperature Conditions ◽  
Hydrogen Bond Networks ◽  
Mild Temperature

Self-healing supramolecular polymers can be rapidly reprocessed under mild temperature conditions via dynamic reshuffling of the hydrogen bond networks.

Hydrogen-Bond-Directed Head-to-Tail Orientation of Dipolar Merocyanine Dyes: A Strategy for the Design of Electrooptical Materials

2006 ◽  
Vol 118 (23) ◽  
pp. 3926-3930 ◽  
Author(s):  
Frank Würthner ◽  
Johann Schmidt ◽  
Matthias Stolte ◽  
Rüdiger Wortmann
Keyword(s):  
Hydrogen Bond ◽  
Merocyanine Dyes

scholarly journals Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning

2015 ◽  
Vol 3 (4) ◽  
pp. 759-768 ◽  
Author(s):  
Marco Saccone ◽  
Valentina Dichiarante ◽  
Alessandra Forni ◽  
Alexis Goulet-Hanssens ◽  
Gabriella Cavallo ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Halogen Bonding ◽  
Surface Patterning ◽  
Supramolecular Polymers ◽  
Hydrogen Bond Donors

Halogen bonding is an interaction of choice in supramolecular polymers for efficient light-induced surface patterning.

Hydrogen-Bond Engineering in Supramolecular Polymers: Polarity Influence on the Self-Assembly of Benzene-1,3,5-tricarboxamides

2010 ◽  
Vol 43 (4) ◽  
pp. 1981-1991 ◽  
Author(s):  
Tristan Mes ◽  
Maarten M. J. Smulders ◽  
Anja R. A. Palmans ◽  
E. W. Meijer
Keyword(s):  
Hydrogen Bond ◽  
Self Assembly ◽  
The Self ◽  
Supramolecular Polymers
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