Synthesis of Polyethylene-Based Proton Exchange Membranes Containing PE Backbone and Sulfonated Poly(arylene ether sulfone) Side Chains for Fuel Cell Applications

2012 ◽  
Vol 45 (5) ◽  
pp. 2460-2470 ◽  
Author(s):  
Hyung Kyu Kim ◽  
Min Zhang ◽  
Xuepei Yuan ◽  
Serguei N. Lvov ◽  
T. C. Mike Chung
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Side Chains ◽  
Arylene Ether ◽  
Sulfonated Poly

Effect of acidification treatment and morphological stability of sulfonated poly(arylene ether sulfone) copolymer proton-exchange membranes for fuel-cell use above 100 °C

2003 ◽  
Vol 41 (22) ◽  
pp. 2816-2828 ◽  
Author(s):  
Yu Seung Kim ◽  
Feng Wang ◽  
Michael Hickner ◽  
Stephan Mccartney ◽  
Young Taik Hong ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Morphological Stability ◽  
Arylene Ether ◽  
Sulfonated Poly

Synthesis and properties of highly branched sulfonated poly(arylene ether)s with flexible alkylsulfonated side chains as proton exchange membranes

2016 ◽  
Vol 4 (6) ◽  
pp. 1326-1335 ◽  
Author(s):  
Dong Liu ◽  
Dan Tao ◽  
Jiangpeng Ni ◽  
Xiongzhi Xiang ◽  
Lei Wang ◽  
...  
Keyword(s):  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Side Chains ◽  
Arylene Ether ◽  
First Time ◽  
Sulfonated Poly

A series of highly branched sulfonated poly(arylene ether)s with flexible alkylsulfonated side chains as proton exchange membranes were synthesized for the first time.

Impact of PVA modified sulfonated poly (arylene ether ketone) copolymers as proton exchange membranes on fuel cell parameters

2021 ◽  
Vol 133 (2) ◽  
Author(s):  
Rashi Dhiman ◽  
Vaishnav Kiran ◽  
Bharti Gaur ◽  
A S Singha
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Cell Parameters ◽  
Arylene Ether ◽  
Ether Ketone ◽  
Sulfonated Poly

Cross-linked aryl-sulfonated poly(arylene ether ketone) proton exchange membranes for fuel cell

2012 ◽  
Vol 63 ◽  
pp. 238-244 ◽  
Author(s):  
Shuhua Zhou ◽  
Dukjoon Kim
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Arylene Ether ◽  
Ether Ketone ◽  
Sulfonated Poly

scholarly journals Highly Proton-Conducting Membranes Based on Poly(arylene ether)s with Densely Sulfonated and Partially Fluorinated Multiphenyl for Fuel Cell Applications

Membranes ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 626
Author(s):  
Tzu-Sheng Huang ◽  
Tung-Li Hsieh ◽  
Chih-Ching Lai ◽  
Hsin-Yi Wen ◽  
Wen-Yao Huang ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Ionic Clusters ◽  
Young’S Moduli ◽  
Arylene Ether ◽  
Transmission Electron ◽  
Conducting Membranes ◽  
Microscopy Images ◽  
Sulfonated Poly

Series of partially fluorinated sulfonated poly(arylene ether)s were synthesized through nucleophilic substitution polycondensation from three types of diols and superhydrophobic tetra-trifluoromethyl-substituted difluoro monomers with postsulfonation to obtain densely sulfonated ionomers. The membranes had similar ion exchange capacities of 2.92 ± 0.20 mmol g−1 and favorable mechanical properties (Young’s moduli of 1.60–1.83 GPa). The membranes exhibited considerable dimensional stability (43.1–122.3% change in area and 42.1–61.5% change in thickness at 80 °C) and oxidative stability (~55.5%). The proton conductivity of the membranes, higher (174.3–301.8 mS cm−1) than that of Nafion 211 (123.8 mS cm−1), was the percent conducting volume corresponding to the water uptake. The membranes were observed to comprise isolated to tailed ionic clusters of size 15–45 nm and 3–8 nm, respectively, in transmission electron microscopy images. A fuel cell containing one such material exhibited high single-cell performance—a maximum power density of 1.32 W cm2 and current density of >1600 mA cm−2 at 0.6 V. The results indicate that the material is a candidate for proton exchange membranes in fuel cell applications.

Preparation and properties of bisphenol A-based sulfonated poly(arylene ether sulfone) proton exchange membranes for direct methanol fuel cell

2009 ◽  
Vol 114 (1) ◽  
pp. 304-312 ◽  
Author(s):  
Ni Zhang ◽  
Junjing Li ◽  
Xiangyu Wang ◽  
Zhi Xia ◽  
Huiling Liu
Keyword(s):  
Fuel Cell ◽  
Bisphenol A ◽  
Direct Methanol Fuel Cell ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Arylene Ether ◽  
Direct Methanol ◽  
Methanol Fuel Cell ◽  
Sulfonated Poly

Sulfonated poly (arylene ether sulfone) proton exchange membranes for fuel cell applications

2015 ◽  
Vol 4 (4) ◽  
Author(s):  
Vaishnav Kiran ◽  
Bharti Gaur
Keyword(s):  
Fourier Transform ◽  
Fuel Cell ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
Structural Characterization ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Thermal Curing ◽  
Arylene Ether ◽  
Sulfonated Poly

AbstractSulfonated poly (arylene ether sulfone) membranes were synthesized by direct copolymerization of 4,4-bis (4-hydroxyphenyl) valeric acid, 4,4′-difluorodiphenyl sulfone and synthesized sulfonated 6F-bisphenol-A/bisphenol-A as novel proton exchange membranes for fuel cell applications. Prepared membranes were subsequently crosslinked with synthesized 6F-bisphenol-A based epoxy resin (EFN) by thermal curing reaction keeping in view the resilience and toughness of the membranes. The structural characterization was done by using Fourier transform infrared (FTIR),

New sulfonated poly(arylene ether sulfone) copolymers containing phenyl side chains as proton exchange membranes

2016 ◽  
Vol 40 (4) ◽  
pp. 3755-3762 ◽  
Author(s):  
RiMing Chen ◽  
Guang Li
Keyword(s):  
Chemical Structure ◽  
Proton Exchange Membranes ◽  
Proton Exchange ◽  
Side Chains ◽  
Arylene Ether ◽  
Phase Images ◽  
Sulfonated Poly

The chemical structure and phase images of the SPAES-PQ-40 membrane.

Sign in / Sign up

Export Citation Format

Share Document