Multiple bonds between main-group elements and transition metals. 67. Synthesis of novel half-sandwich rhenium(V) complexes of mono- and bidentate sulfur-containing ligands: x-ray crystal structure of the xanthate-S,S complex (.eta.5-C5Me5)ReCl3(S2CO-c-C6H11)

1989 ◽  
Vol 8 (10) ◽  
pp. 2394-2398 ◽  
Author(s):  
Janos. Takacs ◽  
Paul. Kiprof ◽  
Georg. Weichselbaumer ◽  
Wolfgang A. Herrmann
Keyword(s):  
Crystal Structure ◽  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Sulfur Containing ◽  
Half Sandwich

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX / Multiple Bonds between Main Group Elements and Transition Metals, LXXXIX

1991 ◽  
Vol 46 (6) ◽  
pp. 747-752 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Dieter W. Marz ◽  
Eberhardt Herdtweck
Keyword(s):  
Molecular Structure ◽  
Transition Metals ◽  
Single Crystal ◽  
Main Group ◽  
X Ray Diffraction ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Clean Synthesis

Reaction of (N-trimethylsilyl)-α-aminopicolin with the rhenium(V) oxohalogenide (η5-C5Me5)ReOCl2 (Me = CH3) exemplifies a simple, clean synthesis of imido-metallosiloxanes, compounds of the structure R3SiO—M=N—R′. The compound (η5-C5Me5)ReCl[OSi(CH3)3](NCH2-2-C5H4N) thus formed under HCl elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction).

ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 84. Organoosmium Oxides: Efficient Syntheses and Structures.

ChemInform ◽  
2010 ◽  
Vol 22 (10) ◽  
pp. no-no
Author(s):  
W. A. HERRMANN ◽  
S. J. EDER ◽  
P. KIPROF ◽  
K. RYPDAL ◽  
P. WATZLOWIK
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements
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