Multiple bonds between transition metals and main-group elements. 74. Five-membered rhenacycles through condensation reactions of methyl(trioxo)rhenium(VII) with bidentate ligands. X-ray crystal structures of 8-oxyquinolinato and catecholato complexes

1990 ◽  
Vol 9 (3) ◽  
pp. 782-787 ◽  
Author(s):  
Janos Takacs ◽  
Paul Kiprof ◽  
Juergen Riede ◽  
Wolfgang A. Herrmann
Keyword(s):  
Transition Metals ◽  
Crystal Structures ◽  
Main Group ◽  
Bidentate Ligands ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Condensation Reactions

Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen, LXXXIX / Multiple Bonds between Main Group Elements and Transition Metals, LXXXIX

1991 ◽  
Vol 46 (6) ◽  
pp. 747-752 ◽  
Author(s):  
Wolfgang A. Herrmann ◽  
Dieter W. Marz ◽  
Eberhardt Herdtweck
Keyword(s):  
Molecular Structure ◽  
Transition Metals ◽  
Single Crystal ◽  
Main Group ◽  
X Ray Diffraction ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
X Ray ◽  
Clean Synthesis

Reaction of (N-trimethylsilyl)-α-aminopicolin with the rhenium(V) oxohalogenide (η5-C5Me5)ReOCl2 (Me = CH3) exemplifies a simple, clean synthesis of imido-metallosiloxanes, compounds of the structure R3SiO—M=N—R′. The compound (η5-C5Me5)ReCl[OSi(CH3)3](NCH2-2-C5H4N) thus formed under HCl elimination has a square-pyramidal molecular structure (single crystal X-ray diffraction).

Multiple bonds between main-group elements and transition metals. 77. Condensation reactions of methyltrioxorhenium(VII) with catechols and aromatic thiols

1991 ◽  
Vol 10 (1) ◽  
pp. 316-320 ◽  
Author(s):  
Janos. Takacs ◽  
Malcolm R. Cook ◽  
Paul. Kiprof ◽  
Josef G. Kuchler ◽  
Wolfgang A. Herrmann
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements ◽  
Condensation Reactions ◽  
Aromatic Thiols

ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 84. Organoosmium Oxides: Efficient Syntheses and Structures.

ChemInform ◽  
2010 ◽  
Vol 22 (10) ◽  
pp. no-no
Author(s):  
W. A. HERRMANN ◽  
S. J. EDER ◽  
P. KIPROF ◽  
K. RYPDAL ◽  
P. WATZLOWIK
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements

ChemInform Abstract: Multiple Bonds Between Main Group Elements and Transition Metals. Part 35. First Four-Membered Metallacycles of Rhenium.

ChemInform ◽  
1987 ◽  
Vol 18 (18) ◽  
Author(s):  
H. J. R. DE BOER ◽  
B. J. J. VAN DE HEISTEEG ◽  
M. FLOEEL ◽  
W. A. HERRMANN ◽  
O. S. AKKERMAN ◽  
...  
Keyword(s):  
Transition Metals ◽  
Main Group ◽  
Multiple Bonds ◽  
Main Group Elements
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