Toward the Synthesis of Indenyl Molybdenum Compound [(η3-Ind)(η5-Cp)Mo(CO)2]: Modified Compounds and Structure of a Previously Unrecognized Intermediate

2013 ◽  
Vol 32 (12) ◽  
pp. 3502-3511 ◽  
Author(s):  
Jan Honzíček ◽  
Jaromír Vinklárek ◽  
Milan Erben ◽  
Jakub Lodinský ◽  
Libor Dostál ◽  
...  
Keyword(s):  
Molybdenum Compound

scholarly journals Impact of Molybdenum Compounds as Anticancer Agents

2019 ◽  
Vol 2019 ◽  
pp. 1-9
Author(s):  
Ayodele T. Odularu ◽  
Peter A. Ajibade ◽  
Johannes Z. Mbese
Keyword(s):  
Breast Cancer ◽  
Drug Design ◽  
Combination Therapy ◽  
Physicochemical Properties ◽  
Case Studies ◽  
Anticancer Drug ◽  
Oesophageal Cancer ◽  
Anticancer Agents ◽  
Cancer Disease ◽  
Molybdenum Compound

The aim of this mini review was to report the molybdenum compound intervention to control cancer disease. The intervention explains its roles and progress from inorganic molybdenum compounds via organomolybdenum complexes to its nanoparticles to control oesophageal cancer and breast cancer as case studies. Main contributions of molybdenum compounds as anticancer agents could be observed in their nanofibrous support with suitable physicochemical properties, combination therapy, and biosensors (biomarkers). Recent areas in anticancer drug design, which entail the uses of selected targets, were also surveyed and proposed.

Tribological properties of sulfur- and phosphorus-free organic molybdenum compound as additive in oil

2020 ◽  
Vol 141 ◽  
pp. 105944
Author(s):  
Wenjuan Huai ◽  
Xinchun Chen ◽  
Fei Lu ◽  
Chenhui Zhang ◽  
Liran Ma ◽  
...  
Keyword(s):  
Tribological Properties ◽  
Molybdenum Compound

Methylenverbindungen von Nichtmetallen, III [1]. Metallcarbonyl-Komplexe mit methylenverbrückten Diphosphor-Liganden / Methylene Compounds of Non-Metals, III [1] Metal Carbonyl Complexes of Methylene-Bridged Diphosphorus Ligands

1980 ◽  
Vol 35 (7) ◽  
pp. 838-842 ◽  
Author(s):  
Manfred Fild ◽  
Wolfgang Handke ◽  
William S. Sheldrick
Keyword(s):  
Metal Carbonyl ◽  
Bidentate Ligand ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Molybdenum Compound

Compounds of the type R2PCH2PR2 (R = PriO, Me2N) react with cis-LM(CO)4 (L = Bicyclo[2,2,1]hepta-2,5-dien; M = Cr, Mo, W) complexes to yield cis-substituted [R2PCH2PR2]M(CO)4 derivatives. The structure of the molybdenum compound, [(PriO)2PCH2P(OPri)2]Mo(CO)4, has been determined. Diphosphorus ligands of the type R2P(S)CH2PR2 (R = F, PriO) are monodentate and form [R2P(S)CH2PR2]2Mo(CO)4 complexes, whereas the compound (Me2N)2P(S)CH2P(NMe2)2 acts as a bidentate ligand

scholarly journals Molybdenum Oxide and Nickel Nitrate as Cooperative Sintering Aids for Yttria-Stabilized Zirconia

Materials ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 2875
Author(s):  
Clay Hunt ◽  
John Kyle Allemeier ◽  
David Driscoll ◽  
Adam Weisenstein ◽  
Stephen Sofie
Keyword(s):  
Crystal Structure ◽  
Sintering Temperature ◽  
Yttria Stabilized Zirconia ◽  
Spontaneous Generation ◽  
Sintering Aids ◽  
Stabilized Zirconia ◽  
Sintering Aid ◽  
Molybdenum Compound ◽  
Order Of Magnitude ◽  
Nano Rods

The entirely accidental observation of increased sintering performance of nickel-infiltrated yttria-stabilized zirconia (8YSZ) in a molybdenum and oxygen rich atmosphere was explored. Molybdenum and nickel were found to be synergistic sintering aids for 8YSZ. However, sintering had to take place in an atmosphere of flowing oxygen. Samples sintered in air consistently burst. The sintering performance, microstructure, and crystal structure of 8YSZ with additions of both Mo and Ni together are compared to the sintering performance, microstructure, and crystal structure of pure 8YSZ, 8YSZ with only Ni added as a sintering aid, and 8YSZ with only Mo added as a sintering aid. Enhanced densification and grain growth is observed in the Mo–Ni 8YSZ samples when compared to all other sintering samples. Order of magnitude sintering rate increases are observed in the Mo–Ni 8YSZ over that of pure 8YSZ. With a maximum sintering temperature of 1200 °C and a one-hour dwell, sintered densities of 85% theoretical density (5.02 g⁄cm3) are achieved with the Mo–Ni samples: a 57% increase in density over pure 8YSZ sintered with the same sintering profile. EIS results suggest conductivity may not be negatively impacted by the use of these two sintering aids at temperatures above 750 °C. Finally, the spontaneous generation of nickel-molybdenum nano-rods was observed on the 5, and 10 mol.% Mo–Ni infiltrated 8YSZ samples after being left under vacuum in a scanning electron microscope chamber, suggesting evaporation of a possible nickel–molybdenum compound from the sample fracture surfaces.

Spectral properties and structure of a mixed valence molybdenum compound

1974 ◽  
Vol 36 (12) ◽  
pp. 3870-3871 ◽  
Author(s):  
C. Heitner-Wirguin ◽  
Dorrit Hall
Keyword(s):  
Spectral Properties ◽  
Mixed Valence ◽  
Molybdenum Compound

Synthesis of the cyanamide-derived bis(cyanoimido) complexes trans-[M(NCN)2(Ph2PCH2CH2PPh2)2] (M = Mo or W) and crystal structure of the molybdenum compound

1989 ◽  
Vol 371 (3) ◽  
pp. C45-C47 ◽  
Author(s):  
Armando J.L. Pombeiro ◽  
M.Fatima C.G. Silva ◽  
David L. Hughes ◽  
Raymond L. Richards
Keyword(s):  
Crystal Structure ◽  
Molybdenum Compound
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