Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic carbenes and their application in aqua-phase Suzuki–Miyaura cross-coupling reaction and transfer hydrogenation

2012 ◽  
Vol 41 (48) ◽  
pp. 14557 ◽  
Author(s):  
Xu-Qing Guo ◽  
Ya-Nong Wang ◽  
Dong Wang ◽  
Li-Hua Cai ◽  
Zhen-Xia Chen ◽  
...  
Keyword(s):  
Ruthenium Complexes ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Heterocyclic Carbenes ◽  
Transfer Hydrogenation ◽  
Cross Coupling Reaction

ChemInform Abstract: A General Approach to N-Heterocyclic Carbenes with a Fused Tetracyclic Core: Ligands for Suzuki-Miyaura Cross-Coupling Reaction.

ChemInform ◽  
2015 ◽  
Vol 46 (8) ◽  
pp. no-no
Author(s):  
Revannath L. Sutar ◽  
Vinod Kumar ◽  
Rahul D. Shingare ◽  
Shridhar Thorat ◽  
Rajesh Gonnade ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Heterocyclic Carbenes ◽  
Cross Coupling Reaction ◽  
Tetracyclic Core

A General Approach to N-Heterocyclic Carbenes with a Fused Tetracyclic Core: Ligands for Suzuki-Miyaura Cross-Coupling Reaction

2014 ◽  
Vol 2014 (21) ◽  
pp. 4482-4486 ◽  
Author(s):  
Revannath L. Sutar ◽  
Vinod Kumar ◽  
Rahul D. Shingare ◽  
Shridhar Thorat ◽  
Rajesh Gonnade ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Heterocyclic Carbenes ◽  
Cross Coupling Reaction ◽  
Tetracyclic Core

Triazine-wingtips accelerated NHC-Pd catalysed carbonylative Sonogashira cross-coupling reaction

2021 ◽  
Author(s):  
Kan Zhang ◽  
Yanxiu Yao ◽  
Winjin Sun ◽  
Rui Wen ◽  
Yanyan Wang ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Heterocyclic Carbenes ◽  
Rate Limiting Step ◽  
Limiting Step ◽  
Cross Coupling Reaction ◽  
Efficient Coupling ◽  
Wing Tips ◽  
Rate Limiting ◽  
Ppm Level

The transmetalation as the rate-limiting step was effectively accelerated by newly designed N-heterocyclic carbenes with triazine wing-tips (T-NHC). By using ppm-level precatalyst T-NHC-Pd (8), the highly efficient coupling of aryl...

Ferromagnetic Chain Based on Verdazyl-Nitroxide Diradical

2020 ◽  
Author(s):  
Evgeny Tretyakov ◽  
Svetlana Zhivetyeva ◽  
Pavel Petunin ◽  
Dmitry Gorbunov ◽  
Nina Gritsan ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Ferromagnetic Coupling ◽  
Nitronyl Nitroxide ◽  
Triplet Ground State ◽  
One Dimensional ◽  
Cross Coupling Reaction ◽  
Palladium Catalyzed ◽  
Ferromagnetic Chain ◽  
High Yields

<p>Verdazyl-nitroxide diradicals were synthesized using the palladium-catalyzed cross-coupling reaction of the corresponding iodoverdazyls with a nitronyl nitroxide-2-ide gold(I) complex with high yields (up to 82%). The synthesized diradicals were found to be highly thermally stable and have a singlet (D<i>E</i><sub>ST</sub> » -64 cm<sup>–1</sup>) or triplet ground state (D<i>E</i><sub>ST</sub> ³ 25 and 100 cm<sup>–1</sup>), depending on which canonical hydrocarbon diradical type they belong to. Upon crystallization, triplet diradicals form unique one-dimensional (1D) spin <i>S</i> = 1 chains of organic diradicals with intrachain ferromagnetic coupling of <i>J</i>′/<i>k</i><sub>B</sub> from 3 to 6 K.</p>

An Iron-Based Catalyst Enables The Enantioconvergent Synthesis of Chiral 1,1-Diarylalkanes Through a Suzuki-Miyaura Cross-Coupling Reaction

2020 ◽  
Author(s):  
Chet Tyrol ◽  
Nang Yone ◽  
Connor Gallin ◽  
Jeffery Byers
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Radical Intermediates ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Boronic Esters ◽  
Carbon Centered Radical ◽  
Iron Based ◽  
High Yields

By using an iron-based catalyst, access to enantioenriched 1,1-diarylakanes was enabled through an enantioselective Suzuki-Miyaura crosscoupling reaction. The combination of a chiral cyanobis(oxazoline) ligand framework and 1,3,5-trimethoxybenzene additive were essential to afford high yields and enantioselectivities in cross-coupling reactions between unactivated aryl boronic esters and a variety of benzylic chlorides, including challenging ortho-substituted benzylic chloride substrates. Mechanistic investigations implicate a stereoconvergent pathway involving carbon-centered radical intermediates.

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