Intramolecular C−C Bond Formation from β-Keto Phosphine and Allenylidene Ligands in Related Ruthenium(II) Cyclopentadienyl and Indenyl Complexes. X-ray Crystal Structure of (SRu,RC/RRu,SC)- [Ru(η5-C9H7)(PPh3){η2(P,O)-Ph2PCH(Me)C(But)O}][PF6] and (SRu,RC/RRu,SC)- [Ru{η2(C,P)-C(CCPh2)CH[C(O)But]PPh2}(η5-C9H7)(PPh3)]

1997 ◽  
Vol 16 (25) ◽  
pp. 5406-5415 ◽  
Author(s):  
Pascale Crochet ◽  
Bernard Demerseman ◽  
M. Isabel Vallejo ◽  
M. Pilar Gamasa ◽  
José Gimeno ◽  
...  





2020 ◽  
Vol 56 (55) ◽  
pp. 7617-7620 ◽  
Author(s):  
Sisi Gao ◽  
Ashish Radadiya ◽  
Wenbo Li ◽  
Huanting Liu ◽  
Wen Zhu ◽  
...  

X-Ray crystal structure of a novel C-glycoside synthase involved in the biosynthesis of biologically active C-nucleosides and C-nucleotides.







2018 ◽  
Vol 14 ◽  
pp. 1287-1292 ◽  
Author(s):  
Gernot A Eller ◽  
Gytė Vilkauskaitė ◽  
Algirdas Šačkus ◽  
Vytas Martynaitis ◽  
Ashenafi Damtew Mamuye ◽  
...  

Dialkyl 5,5'-dioxo-4,4'-bipyrazole-4,4'-dicarboxylates are readily obtained by the reaction of 5-hydroxypyrazole-4-carboxylates in refluxing thionyl chloride. The obtained diesters can be transformed into the corresponding 4,4'-bipyrazoles via alkaline hydrolysis and subsequent decarboxylation. Detailed NMR spectroscopic investigations (1H, 13C, 15N) were undertaken with all products prepared. Moreover, the structure of a representative 5,5'-dioxo-4,4'-bipyrazole-4,4'-dicarboxylate was confirmed by X-ray crystal structure analysis.







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