scholarly journals Electrodeposition of hierarchically structured three-dimensional nickel–iron electrodes for efficient oxygen evolution at high current densities

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Xunyu Lu ◽  
Chuan Zhao
Keyword(s):  
Oxygen Evolution ◽  
Three Dimensional ◽  
High Current ◽  
Nickel Iron ◽  
Iron Electrodes ◽  
Current Densities

scholarly journals A Superaerophobic Bimetallic Selenides Heterostructure for Efficient Industrial-Level Oxygen Evolution at Ultra-High Current Densities

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Jiaxin Yuan ◽  
Xiaodi Cheng ◽  
Hanqing Wang ◽  
Chaojun Lei ◽  
Sameer Pardiwala ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Active Sites ◽  
Electronic Conductivity ◽  
Three Dimensional ◽  
Active Surface ◽  
Alkaline Media ◽  
Active Surface Area ◽  
High Current ◽  
High Electronic Conductivity ◽  
Current Densities

AbstractCost-effective and stable electrocatalysts with ultra-high current densities for electrochemical oxygen evolution reaction (OER) are critical to the energy crisis and environmental pollution. Herein, we report a superaerophobic three dimensional (3D) heterostructured nanowrinkles of bimetallic selenides consisting of crystalline NiSe2 and NiFe2Se4 grown on NiFe alloy (NiSe2/NiFe2Se4@NiFe) prepared by a thermal selenization procedure. In this unique 3D heterostructure, numerous nanowrinkles of NiSe2/NiFe2Se4 hybrid with a thickness of ~ 100 nm are grown on NiFe alloy in a uniform manner. Profiting by the large active surface area and high electronic conductivity, the superaerophobic NiSe2/NiFe2Se4@NiFe heterostructure exhibits excellent electrocatalytic activity and durability towards OER in alkaline media, outputting the low potentials of 1.53 and 1.54 V to achieve ultra-high current densities of 500 and 1000 mA cm−2, respectively, which is among the most active Ni/Fe-based selenides, and even superior to the benchmark Ir/C catalyst. The in-situ derived FeOOH and NiOOH species from NiSe2/NiFe2Se4@NiFe are deemed to be efficient active sites for OER.

Highly Stable Three-Dimensional Porous Nickel-Iron Nitride Nanosheets for Full Water Splitting at High Current Densities

2017 ◽  
Vol 23 (42) ◽  
pp. 10187-10194 ◽  
Author(s):  
Feng Yan ◽  
Yue Wang ◽  
Kaiyue Li ◽  
Chunling Zhu ◽  
Peng Gao ◽  
...  
Keyword(s):  
Water Splitting ◽  
Three Dimensional ◽  
Iron Nitride ◽  
High Current ◽  
Porous Nickel ◽  
Nickel Iron ◽  
Current Densities

scholarly journals CoFe–OH Double Hydroxide Films Electrodeposited on Ni-Foam as Electrocatalyst for the Oxygen Evolution Reaction

2020 ◽  
Vol 234 (5) ◽  
pp. 995-1019 ◽  
Author(s):  
Kirill Sliozberg ◽  
Yauhen Aniskevich ◽  
Ugur Kayran ◽  
Justus Masa ◽  
Wolfgang Schuhmann
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Current ◽  
Ni Foam ◽  
Active Electrode ◽  
Catalyst Film ◽  
Cobalt Iron ◽  
Electrochemically Deposited ◽  
Current Densities ◽  
Double Hydroxide

AbstractCobalt-iron double hydroxide (CoFe–OH) films were electrochemically deposited on 3D Ni foam electrodes for the oxygen evolution reaction (OER). The dependence of the OER activity on film composition and thickness was evaluated, which revealed an optimal Fe:Co ratio of about 1:2.33. The composition of the catalyst film was observed to vary with film thickness. The electrodeposition parameters were carefully controlled to yield microstructured Ni-foam decorated with CoFe–OH films of controlled thickness and composition. The most active electrode exhibited an overpotential as low as 360 mV OER at an industrial scale current density of 400 mA cm−2 that remained stable for at least 320 h. This work contributes towards the fabrication of practical electrodes with the focus on the development of stable electrodes for electrocatalytic oxygen evolution at high current densities.

A strongly coupled 3D ternary Fe2O3@Ni2P/Ni(PO3)2 hybrid for enhanced electrocatalytic oxygen evolution at ultra-high current densities

2019 ◽  
Vol 7 (3) ◽  
pp. 965-971 ◽  
Author(s):  
Xiaodi Cheng ◽  
Zhiyan Pan ◽  
Chaojun Lei ◽  
Yangjun Jin ◽  
Bin Yang ◽  
...  
Keyword(s):  
Strong Coupling ◽  
Oxygen Evolution ◽  
Synergistic Effects ◽  
High Current ◽  
Strongly Coupled ◽  
Highly Active ◽  
Current Densities

A ternary Fe2O3@Ni2P/Ni(PO3)2 hybrid with strong coupling and synergistic effects was developed for highly active OER at ultra-high current densities.

Integrative Chemistry-Based Generation of Novel Three Dimensional Macrocellular Carbonaceous Biofuel Cell

2014 ◽  
Vol 1641 ◽  
Author(s):  
Victoria Flexer ◽  
Nicolas Brun ◽  
Mathieu Destribats ◽  
Rénal Backov ◽  
Nicolas Mano
Keyword(s):  
Current Density ◽  
Electrode Material ◽  
Three Dimensional ◽  
Modified Electrodes ◽  
Biofuel Cell ◽  
High Current ◽  
Active Components ◽  
Synthetic Pathway ◽  
Current Densities ◽  
The Right

ABSTRACTHere we report the first membrane-less biofuel cell made by using three-dimensional carbonaceous foam electrodes. We first developed a new synthetic pathway to produce a new carbonaceous foam electrode material with increased porosity both in the meso and macroporous scale. We proved that by increasing the porosity of our three-dimensional foams we could increase the current density of our modified electrodes. Then, by choosing the right combination of enzyme and mediator, and the right loading of active components, we achieved unprecedentedly high current densities for an anodic system. Finally, we combined the improved cathode and anode to build a new membrane-less hybrid enzymatic biofuel cell consisting of a mediated anode and a mediator-less cathode.

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