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2022 ◽  
Vol 9 ◽  
Author(s):  
Leonardo Vivas ◽  
Dinesh Pratap Singh

Inclination to exploit renewable energy and their potential storage by facile, cost-effective, and above all in a green way are exactly what the current alternative energy research is looking for. The high-performance supercapacitor devices made up with the electrode materials synthesized in a simple and ecofriendly way are in utmost demand and the ultimate goal for widespread commercialization. Keeping these points in view, one pot green synthesis of active electrode material rGO-Au composite is achieved which not only performs as a very good supercapacitor in three-electrode configuration but also demonstrates extremely well as a coin cell device, ready to use. Ascorbic acid, which is commonly found in citrus fruits, plays an important role to reduce graphene oxide into rGO and simultaneously gold salt into gold nanoparticles, resulting in rGO-Au composite. The maximum recorded specific capacitance by CV measurement is 303.02 Fg−1 at a scan rate of 5 mVs−1. Hindrance in the commercialization is caused by the differences in the supercapacitor performances between three electrode configurations and finally the proposed device. Here the proposed coin cell device exhibits maximum areal and mass specific capacitance of 62.43 mFcm−2 and 56.09 Fg−1, respectively, that is very high among all reported graphene based composite devices benefitted over with commercially viable high capacity retention up to 80% even after 10,000 cycles. The proposed device demonstrates high energy density (∼ ED = 7.79 Wh/Kg) comparable to batteries and an optimum power density (∼ PD = 2512.9 W/Kg) close to supercapacitor insinuating it is an effective green supercapacitor for commercialization.


2021 ◽  
Vol 23 (1) ◽  
pp. 351
Author(s):  
Jae Sik Kim ◽  
Seong Woo Choi ◽  
Yun-Gwi Park ◽  
Sung Joon Kim ◽  
Chang Heon Choi ◽  
...  

Cardiac radioablation is emerging as an alternative option for refractory ventricular arrhythmias. However, the immediate acute effect of high-dose irradiation on human cardiomyocytes remains poorly known. We measured the electrical activities of human induced pluripotent stem cell-derived cardiomyocytes (iPSC-CMs) upon irradiation with 0, 20, 25, 30, 40, and 50 Gy using a multi-electrode array, and cardiomyocyte function gene levels were evaluated. iPSC-CMs showed to recover their electrophysiological activities (total active electrode, spike amplitude and slope, and corrected field potential duration) within 3–6 h from the acute effects of high-dose irradiation. The beat rate immediately increased until 3 h after irradiation, but it steadily decreased afterward. Conduction velocity slowed in cells irradiated with ≥25 Gy until 6–12 h and recovered within 24 h; notably, 20 and 25 Gy-treated groups showed subsequent continuous increase. At day 7 post-irradiation, except for cTnT, cardiomyocyte function gene levels increased with increasing irradiation dose, but uniquely peaked at 25–30 Gy. Altogether, high-dose irradiation immediately and reversibly modifies the electrical conduction of cardiomyocytes. Thus, compensatory mechanisms at the cellular level may be activated after the high-dose irradiation acute effects, thereby, contributing to the immediate antiarrhythmic outcome of cardiac radioablation for refractory ventricular arrhythmias.


2021 ◽  
Author(s):  
G. Suganya ◽  
M. Arivanandhan ◽  
Kalpana Gopalakrishnan

Abstract Bare PbS QDs and PbS-GQDs nanocomposite were prepared by chemical methods for supercapattery application and characterized by suitable analytical techniques confirming the formation of PbS-GQDs nanocomposite. The electrochemical performance of the fabricated electrodes showed that the PbS-GQDs nanocomposite exhibited high specific capacity, energy and power densities of 577.94 C g-1 , 166.45 Wh kg-1 and 576.01 W kg-1 respectively at 2 A g-1 compared to that of bare PbS QDs. The enhanced electrochemical performance of PbS-GQDs can be associated with the conductive platform provided by synergistic effect of GQDs. The nonlinearity in charge and discharge curves confirms the supercapattery behaviour of the nanocomposite. Also, PbS-G QDs nanocomposite electrode showed highly cyclic stability compared to bare PbS QDs after 5000 cycles. The results emphasize the potential of PbS-G QDs nanocomposite as a stable active electrode material for energy storage application.


2021 ◽  
Vol 23 (6) ◽  
pp. 306-312
Author(s):  
I.V. Mandrik ◽  
◽  
V.A. Startsev ◽  
O.S. Bokhov ◽  
A.V. Pudova ◽  
...  

Flexible printed electronics and photonics technologies are in demand because they are cost-effective and quickly reconfigurable. Zinc-silver battery can help towards development of body conformal wearable electronics. The study evaluate planar sec-ondary Ag2O-Zn battery fabricated using the inkjet printing technology. Polyethylene naphthalate (PEN) is used as polymer substrate and carbon nanotubes material is used as current collectors. The demonstrated battery achieves an capacity of 4 mAh with active electrode area of 14 cm2 and thickness of 0.2 mm.


Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 24
Author(s):  
Amaury Fimbel ◽  
Thierry Abensur ◽  
Minh-Quyen Le ◽  
Jean-Fabien Capsal ◽  
Pierre-Jean Cottinet

Electroadhesion is a phenomenon ruled by many characteristic intrinsic parameters. To achieve a good adhesion, efficient and durable, a particular attention must be provided to the adhesion forces between the involved parts. In addition to the size and geometry of electrodes, parameters of materials such as dielectric constant, breakdown electric field, and Young’s modulus are key factors in the evaluation of electroadhesion efficiency for electrostrictive polymers and electroactive devices. By analyzing these material parameters, a method is proposed to justify the choice of polymer matrices that are fit to specific electroadhesion applications. Another purpose of this work aims to demonstrate a possibility of accurately measuring the electroadhesion force. This physical parameter has been usually estimated through equations instead, because of the complexity in setup implementation to achieve highly precise measure. Comparisons based on the parameters criterion reveal that besides the intrinsic properties of material, some other parameters relating to its physical phenomena (e.g., saturation of dipolar orientation under high electric field leads to decrease dielectric constant), or physical behavior of the system (i.e., surface roughness reduces the active electrode area) must be thoroughly considered. Experimental results pointed out that plasticized terpolymer leads boosted electroadhesion performance compared to the other counterparts, up to 100 times higher than conventional polymers. The developed materials show high potential in applications of active displacement control for electrostrictive actuation.


2021 ◽  
Vol 12 ◽  
Author(s):  
Roberto Esposti ◽  
Silvia M. Marchese ◽  
Veronica Farinelli ◽  
Francesco Bolzoni ◽  
Paolo Cavallari

Evidence shows that the postural and focal components within the voluntary motor command are functionally unique. In 2015, we reported that the supplementary motor area (SMA) processes Anticipatory Postural Adjustments (APAs) separately from the command to focal muscles, so we are still searching for a hierarchically higher area able to process both components. Among these, the parietal operculum (PO) seemed to be a good candidate, as it is a hub integrating both sensory and motor streams. However, in 2019, we reported that transcranial Direct Current Stimulation (tDCS), applied with an active electrode on the PO contralateral to the moving segment vs. a larger reference electrode on the opposite forehead, did not affect intra-limb APAs associated to brisk flexions of the index-finger. Nevertheless, literature reports that two active electrodes of opposite polarities, one on each PO (dual-hemisphere, dh-tDCS), elicit stronger effects than the “active vs. reference” arrangement. Thus, in the present study, the same intra-limb APAs were recorded before, during and after dh-tDCS on PO. Twenty right-handed subjects were tested, 10 for each polarity: anode on the left vs. cathode on the right, and vice versa. Again, dh-tDCS was ineffective on APA amplitude and timing, as well as on prime mover recruitment and index-finger kinematics. These results confirm the conclusion that PO does not take part in intra-limb APA control. Therefore, our search for an area in which the motor command to prime mover and postural muscles are still processed together will have to address other structures.


2021 ◽  
pp. 108425
Author(s):  
Daniele De Seta ◽  
Hannah Daoudi ◽  
Renato Torres ◽  
Evelyne Ferrary ◽  
Olivier Sterkers ◽  
...  

2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Jiezeng Chen ◽  
Hongying Shu ◽  
Pingping Niu ◽  
Pinghua Chen ◽  
Hualin Jiang

Due to the abuse application of antibiotics in the recent decades, a high level of antibiotics has been let out and remains in our environment. Electrochemical sensing is a useful method to sensitively detect antibiotics, and the key factor for a successful electrochemical sensor is the active electrode materials. In this study, a sensitive electrochemical sensing platform based on a metal-organic framework (MOF) of MIL-53 (Fe) was facilely fabricated. It shows highly selective and sensitive detection performance for trace tetracycline. Differential pulse voltammetry (DPV) was applied to analyze the detection of tetracycline. The linear range of tetracycline detection was 0.0643 μmol/L-1.53 μmol/L, and the limit of detection (LOD) is 0.0260 μmol/L. Furthermore, the MOF-enabled sensor can be effectively used in actual water bodies. The results indicate that the electrochemical sensor is a high potential sensing platform for tetracycline.


Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1408
Author(s):  
Mohamed A. Ghanem ◽  
Mabrook S. Amer ◽  
Abdullah M. Al-Mayouf ◽  
Prabhakarn Arunachalam ◽  
Mark T. Weller

Perovskites of strontium cobalt oxyhalides having the chemical formulae Sr2CoO4-xHx (H = F, Cl, and Br; x = 0 and 1) were prepared using a solid-phase synthesis approach and comparatively evaluated as electrocatalysts for oxygen evolution in an alkaline solution. The perovskite electrocatalyst crystal phase, surface morphology, and composition were examined by X-ray diffraction, a scanning electron microscope, and energy-dispersive X-ray (EDX) mapping. The electrochemical investigations of the oxyhalides catalysts showed that the doping of F, Cl, or Br into the Sr2CoO4 parent oxide enhances the electrocatalytic activity for the oxygen evolution reaction (OER) with the onset potential as well as the potential required to achieve a current density of 10 mA/cm2 shifting to lower potential values in the order of Sr2CoO4 (1.64, 1.73) > Sr2CoO3Br (1.61, 1.65) > Sr2CoO3Cl (1.53, 1.60) > Sr2CoO3F (1.50, 1.56) V vs. HRE which indicates that Sr2CoO3F is the most active electrode among the studied catalysts under static and steady-state conditions. Moreover, Sr2CoO3F demonstrates long-term stability and remarkably less charge transfer resistance (Rct = 36.8 ohm) than the other oxyhalide counterparts during the OER. The doping of the perovskites with halide ions particularly the fluoride-ion enhances the surface oxygen vacancy density due to electron withdrawal away from the Co-atom which improves the ionic and electronic conductivity as well as the electrochemical activity of the oxygen evolution in alkaline solution.


Author(s):  
Dhrubajyoti Bhattacharjya ◽  
Maria Arnaiz ◽  
Maria Canal Rodriguez ◽  
Silvia Martin ◽  
Tandra Panja ◽  
...  

Abstract Due to the dual advantage of capacitive and faradaic charge storage mechanisms, Li-ion capacitors (LICs) are regarded as promising energy storage technology for many high-power applications. However, the high cost and intricacy of indispensable pre-lithiation step in LIC fabrication are the major stumbling block against its widespread commercial interest. In this regard, operando pre-lithiation through incorporating lithium-containing sacrificial salt in the positive electrode holds high potential to solve this issue. Herein, we present an industrially compatible fabrication method based on a solution-processable positive electrode consisting of an activated carbon mixed with a low-cost, air-stable dilithium squarate as sacrificial salt. Through careful optimization of electrode design, laboratory-scale cells are up-scaled to pouch cell prototypes. Fabricated LIC pouch cells deliver high specific energy (i.e. max. 58 Wh kg-1AM) and power (i.e. max. 8190 W kg-1AM) with respect to active electrode mass. Moreover, cycle life and floating tests performed at room temperature show capacitance retention of 83 % after 80000 charge-discharge cycles and 100 % retention after 1000 floating hours at 3.8 V. However, the accelerated aging tests at 70 ºC induce fast device failure. Post-mortem analyses reveal different ageing mechanisms for cycled and floated LIC pouch cells.


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