scholarly journals Kinetics and mechanism of the reaction between atomic chlorine and dimethyl selenide; comparison with the reaction between atomic chlorine and dimethyl sulfide

2002 ◽  
Vol 4 (17) ◽  
pp. 4133-4139 ◽  
Author(s):  
Katherine C. Thompson ◽  
Carlos E. Canosa-Mas ◽  
Richard P. Wayne
Keyword(s):  
Dimethyl Sulfide ◽  
Kinetics And Mechanism ◽  
Dimethyl Selenide ◽  
Atomic Chlorine ◽  
Mechanism Of The Reaction

A Fourier-transform infrared study of the kinetics and mechanism of the reaction of atomic chlorine with dimethylmercury

1983 ◽  
Vol 87 (19) ◽  
pp. 3722-3724 ◽  
Author(s):  
H. Niki ◽  
P. S. Maker ◽  
C. M. Savage ◽  
L. P. Breitenbach
Keyword(s):  
Fourier Transform ◽  
Fourier Transform Infrared ◽  
Kinetics And Mechanism ◽  
Infrared Study ◽  
Atomic Chlorine ◽  
Mechanism Of The Reaction

Kinetics and mechanism of the reaction of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione

1990 ◽  
Vol 55 (8) ◽  
pp. 1984-1990 ◽  
Author(s):  
José M. Hernando ◽  
Olimpio Montero ◽  
Carlos Blanco
Keyword(s):  
Aqueous Solution ◽  
Metal Ion ◽  
Activation Parameters ◽  
Enol Form ◽  
Kinetics And Mechanism ◽  
Kinetic Constants ◽  
Steric Factors ◽  
Kinetics Of ◽  
Mechanism Of The Reaction

The kinetics of the reactions of iron(III) with 6-methyl-2,4-heptanedione and 3,5-heptanedione to form the corresponding monocomplexes have been studied spectrophotometrically in the range 5 °C to 16 °C at I 25 mol l-1 in aqueous solution. In the proposed mechanism for the two complexes, the enol form reacts with the metal ion by parallel acid-independent and inverse-acid paths. The kinetic constants for both pathways have been calculated at five temperatures. Activation parameters have also been calculated. The results are consistent with an associative activation for Fe(H2O)63+ and dissociative activation for Fe(H2O)5(OH)2+. The differences in the results for the complexes of heptanediones studied are interpreted in terms of steric factors.

Kinetics and mechanism of the reaction of OH with ClO

2001 ◽  
Vol 33 (10) ◽  
pp. 587-599 ◽  
Author(s):  
Yuri Bedjanian ◽  
V�ronique Riffault ◽  
Georges Le Bras
Keyword(s):  
Kinetics And Mechanism ◽  
Mechanism Of The Reaction

A Theoretical Investigation on the Kinetics and Mechanism of the Reaction of Amidogen with Hydroxyl Radical

2009 ◽  
Vol 113 (46) ◽  
pp. 12961-12971 ◽  
Author(s):  
S. Hosein Mousavipour ◽  
Fatemeh Pirhadi ◽  
Arezoo HabibAgahi
Keyword(s):  
Hydroxyl Radical ◽  
Theoretical Investigation ◽  
Kinetics And Mechanism ◽  
Mechanism Of The Reaction

ChemInform Abstract: Kinetics and Mechanism of the Reaction of Ozone with Aliphatic Alcohols (I)-(V).

ChemInform ◽  
1990 ◽  
Vol 21 (27) ◽  
Author(s):  
S. RAKOVSKI ◽  
D. CHERNEVA
Keyword(s):  
Aliphatic Alcohols ◽  
Kinetics And Mechanism ◽  
Mechanism Of The Reaction

Kinetics and mechanism of the reaction between vanadium(II) and chromium(VI)

1972 ◽  
Vol 11 (10) ◽  
pp. 2494-2499 ◽  
Author(s):  
Kenneth L. Bridges ◽  
Samir K. Mukherjee ◽  
Gilbert. Gordon
Keyword(s):  
Kinetics And Mechanism ◽  
Chromium Vi ◽  
Mechanism Of The Reaction
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