A three-dimensional porous metal–organic framework with the rutile topology constructed from triangular and distorted octahedral building blocks

2005 ◽  
pp. 2402 ◽  
Author(s):  
Linhua Xie ◽  
Shuxia Liu ◽  
Bo Gao ◽  
Chundan Zhang ◽  
Chunyan Sun ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Building Blocks ◽  
Distorted Octahedral ◽  
Metal Organic ◽  
Organic Framework

A three-dimensional porous metal–organic framework of unusual rob topology based on a novel fluorinated bis(imidazole) ligand

2011 ◽  
Vol 14 (11) ◽  
pp. 1819-1822 ◽  
Author(s):  
Zhi-Hui Zhang ◽  
Sheng-Chun Chen ◽  
Qun Chen ◽  
Ming-Yang He ◽  
Huan Xu
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Imidazole Ligand ◽  
Metal Organic ◽  
Organic Framework

Synthesis, Structure, and Properties of a Chiral Zinc(II) Metal-Organic Framework Featuring Linear Trinuclear Secondary Building Blocks

2012 ◽  
Vol 65 (12) ◽  
pp. 1662 ◽  
Author(s):  
Zilu Chen ◽  
Chuanbing Zhang ◽  
Xianlin Liu ◽  
Zhong Zhang ◽  
Fupei Liang
Keyword(s):  
Building Block ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Triangular Prism ◽  
Structure And Properties ◽  
Adsorption Selectivity ◽  
One Dimensional ◽  
Metal Organic ◽  
Organic Framework

A chiral metal-organic framework formulated as [Zn3(L-TMTA)2(4,4′-bpy)4]·24H2O (1) was prepared from the reaction of Zn(NO3)2·6H2O with trimesoyltri(L-alanine) (L-TMTAH3) in the presence of 4,4′-bipyridine (4,4′-bpy). Compound 1 features linear trinuclear secondary building blocks [Zn3(syn-syn-COO)2(μ2,η3-COO)2]2+. Each linear trinuclear secondary building block is further linked to another eight ones around it by four L-TMTA3– ligands and eight 4,4′-bpy ligands, leading to the construction of a uninodal three-dimensional framework with triangular prism-like one-dimensional channels. Dehydrated compound 1 displays remarkable adsorption selectivity on CO2 and water vapour over N2 gas.

Direct synthesis of N-sulfenylimines through oxidative coupling of amines with disulfides/thiols over copper based metal–organic frameworks

RSC Advances ◽  
2016 ◽  
Vol 6 (47) ◽  
pp. 40945-40952 ◽  
Author(s):  
Wei Long ◽  
Wenge Qiu ◽  
Chuanqiang Li ◽  
Liyun Song ◽  
Guangmei Bai ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Metal Organic Framework ◽  
Direct Synthesis ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework based on supramolecular building blocks with pcu-topology has been tested for the oxidative coupling of amines and disulfides to afford the N-sulfenylimines directly in good yields.

An Adeninate-Based Metal–Organic Framework for Antitumour Drug Delivery and Anti-Osteogenic Sarcoma Activity Evolution

2018 ◽  
Vol 71 (12) ◽  
pp. 978
Author(s):  
Bing Yan ◽  
Huanqiu Li ◽  
Wenyan Jiang ◽  
Long Mu
Keyword(s):  
Drug Delivery ◽  
Ph Value ◽  
Antitumour Activity ◽  
Metal Organic Framework ◽  
Osteogenic Sarcoma ◽  
Three Dimensional ◽  
Building Blocks ◽  
Therapy Effect ◽  
Metal Organic ◽  
Organic Framework

Targeted anticancer drug delivery systems (DDSs) have been considered as one of the most important approaches for reducing the side effects and enhancing the therapy effect in cancer treatment. This work presents a targeted anticancer DDS on the basis of a newly synthesised adeninate-based metal–organic framework (MOF) [Zn2(ad)2(AMDB)(H2O)](DMF)3 (1) with biomolecular adenine (HAd), zinc(ii) ions, and 4,4′-(aminomethylene)dibenzoic acid (H2AMDB) as the molecular building blocks. The structural analysis via X-ray diffraction technology shows MOF 1 is a channel-type three-dimensional network composed of rod-like Zn–Ad chains. Due to its large inner free spaces and uncoordinated N donor sites functionalised pore surroundings, the antitumour molecule 5-fluorouracil (5-Fu) could be loaded into the pores of 1a (activated 1) though an adsorption process, which shows a moderate high storage capacity of 32 wt-%. At the same time, the pH-dependent delivery of 5-Fu could be achieved in phosphate-buffered saline (PBS) solution. With a lower pH value, the drug release will be enhanced. Furthermore, the invitro antitumour activity of the drug/1a composite has been probed via 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay on two human osteogenic sarcoma cells (MG63 and U2OS).

A Three-Dimensional Porous Metal−Organic Framework Constructed from Two-Dimensional Sheets via Interdigitation Exhibiting Dynamic Features

2009 ◽  
Vol 48 (11) ◽  
pp. 4616-4618 ◽  
Author(s):  
Shengqian Ma ◽  
Daofeng Sun ◽  
Paul M. Forster ◽  
Daqiang Yuan ◽  
Wenjuan Zhuang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Two Dimensional ◽  
Dynamic Features ◽  
Metal Organic ◽  
Organic Framework

A three-dimensional non-interpenetrated porous metal–organic framework based on cationic 1-D chains

2014 ◽  
Vol 40 ◽  
pp. 148-150 ◽  
Author(s):  
Jian-Liang Zhou ◽  
Yuan-Yuan Wang ◽  
Min-Jia Zhou ◽  
Ling Qin ◽  
Ming-Dao Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Control of interpenetration in a microporous metal–organic framework for significantly enhanced C2H2/CO2 separation at room temperature

2016 ◽  
Vol 52 (17) ◽  
pp. 3494-3496 ◽  
Author(s):  
Ganggang Chang ◽  
Bin Li ◽  
Hailong Wang ◽  
Tongliang Hu ◽  
Zongbi Bao ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Co2 Separation ◽  
Reaction Conditions ◽  
Metal Organic ◽  
Organic Framework

A novel non-interpenetrated three-dimensional porous metal–organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions.

scholarly journals Metal-organic framework based on hinged cube tessellation as transformable mechanical metamaterial

2019 ◽  
Vol 5 (5) ◽  
pp. eaav4119 ◽  
Author(s):  
Eunji Jin ◽  
In Seong Lee ◽  
Dongwook Kim ◽  
Hosoowi Lee ◽  
Woo-Dong Jang ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Building Blocks ◽  
Three Dimensional Printing ◽  
Detailed Structural Analysis ◽  
Mechanical Metamaterials ◽  
Metal Organic ◽  
New Type ◽  
Organic Framework

Mechanical metamaterials exhibit unusual properties, such as negative Poisson’s ratio, which are difficult to achieve in conventional materials. Rational design of mechanical metamaterials at the microscale is becoming popular partly because of the advance in three-dimensional printing technologies. However, incorporating movable building blocks inside solids, thereby enabling us to manipulate mechanical movement at the molecular scale, has been a difficult task. Here, we report a metal-organic framework, self-assembled from a porphyrin linker and a new type of Zn-based secondary building unit, serving as a joint in a hinged cube tessellation. Detailed structural analysis and theoretical calculation show that this material is a mechanical metamaterial exhibiting auxetic behavior. This work demonstrates that the topology of the framework and flexible hinges inside the structure are intimately related to the mechanical properties of the material, providing a guideline for the rational design of mechanically responsive metal-organic frameworks.

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