Alkenylation of allylic alcohols using alkenylboron dihalides: a formal transition-metal free Suzuki reaction

Chemical Communications ◽

10.1039/b502026c ◽

2005 ◽

pp. 2492 ◽

Author(s):

George W. Kabalka ◽

Min-Liang Yao ◽

Scott Borella ◽

Zhongzhi Wu

Keyword(s):

Transition Metal ◽

Suzuki Reaction ◽

Allylic Alcohols ◽

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Alkenylation of Allylic Alcohols Using Alkenylboron Dihalides: A Formal Transition-Metal Free Suzuki Reaction.

10.1002/chin.200538101 ◽

2005 ◽

Vol 36 (38) ◽

Author(s):

George W. Kabalka ◽

Min-Liang Yao ◽

Scott Borella ◽

Zhongzhi Wu

Keyword(s):

Transition Metal ◽

Suzuki Reaction ◽

Allylic Alcohols ◽

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Transition metal-free, NaOtBu-O2-mediated one-pot cascade oxidation of allylic alcohols to α,β-unsaturated carboxylic acids

Green Chemistry ◽

10.1039/c2gc36203a ◽

2012 ◽

Vol 14 (11) ◽

pp. 2996 ◽

Author(s):

Sun Min Kim ◽

Young Sug Kim ◽

Dong Wan Kim ◽

Jung Woon Yang

Keyword(s):

Transition Metal ◽

Carboxylic Acids ◽

Allylic Alcohols ◽

One Pot ◽

Unsaturated Carboxylic Acids

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ChemInform Abstract: Transition Metal-Free, NaOtBu-O2-Mediated One-Pot Cascade Oxidation of Allylic Alcohols to α,β-Unsaturated Carboxylic Acids.

10.1002/chin.201311067 ◽

2013 ◽

Vol 44 (11) ◽

pp. no-no

Author(s):

Sun Min Kim ◽

Young Sug Kim ◽

Dong Wan Kim ◽

Jung Woon Yang

Keyword(s):

Transition Metal ◽

Carboxylic Acids ◽

Allylic Alcohols ◽

One Pot ◽

Unsaturated Carboxylic Acids

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Difluoroalkylation/1,2-Aryl Migration of Allylic Alcohols Under Transition Metal-Free Conditions

Tetrahedron Letters ◽

10.1016/j.tetlet.2021.153002 ◽

2021 ◽

pp. 153002

Author(s):

Danhua Ge ◽

Xin Wang ◽

Xue-Qiang Chu

Keyword(s):

Transition Metal ◽

Allylic Alcohols ◽

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Mild Two-Step Process for the Transition-Metal-Free Synthesis of Carbon−Carbon Bonds from Allylic Alcohols/Ethers and Grignard Reagents

Journal of the American Chemical Society ◽

10.1021/ja100747n ◽

2010 ◽

Vol 132 (12) ◽

pp. 4104-4106 ◽

Author(s):

Xinping Han ◽

Yanhua Zhang ◽

Jimmy Wu

Keyword(s):

Transition Metal ◽

Grignard Reagents ◽

Allylic Alcohols ◽

Step Process ◽

Carbon Carbon Bonds ◽

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ChemInform Abstract: Mild Two-Step Process for the Transition-Metal-Free Synthesis of Carbon-Carbon Bonds from Allylic Alcohols/Ethers and Grignard Reagents.

10.1002/chin.201033040 ◽

2010 ◽

Vol 41 (33) ◽

pp. no-no

Author(s):

Xinping Han ◽

Yanhua Zhang ◽

Jimmy Wu

Keyword(s):

Transition Metal ◽

Grignard Reagents ◽

Allylic Alcohols ◽

Step Process ◽

Carbon Carbon Bonds ◽

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Transition-Metal-Free, TsOH-Mediated Direct C−H Allylation of 1,4-Benzoquinone with Allylic Alcohols

Asian Journal of Organic Chemistry ◽

10.1002/ajoc.201800177 ◽

2018 ◽

Vol 7 (7) ◽

pp. 1385-1389 ◽

Author(s):

Qingjuan Han ◽

Kun Jiang ◽

Ye Wei ◽

Weiping Su

Keyword(s):

Transition Metal ◽

Allylic Alcohols ◽

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Transition-metal-free catalytic hydroboration reduction of amides to amines

Organic Chemistry Frontiers ◽

10.1039/d0qo01092h ◽

2020 ◽

Vol 7 (21) ◽

pp. 3515-3520

Author(s):

Wubing Yao ◽

Jiali Wang ◽

Aiguo Zhong ◽

Shiliang Wang ◽

Yinlin Shao

Keyword(s):

Transition Metal ◽

Selective Catalytic Reduction ◽

Catalytic Reduction ◽

Value Added ◽

The selective catalytic reduction of amides to value-added amine products is a desirable but challenging transformation.

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Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

Organic Chemistry Frontiers ◽

10.1039/d0qo01479f ◽

2021 ◽

Author(s):

Fengqian Zhao ◽

Xiao-Feng Wu

Keyword(s):

Free Radical ◽

Transition Metal ◽

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.

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Regioselective C3-H Trifluoromethylation of 2H-Indazole Under Transition-Metal-Free Photoredox Catalysis

10.26434/chemrxiv.7796603.v1 ◽

2019 ◽

Author(s):

Arumugavel Murugan ◽

Venkata Nagarjuna Babu ◽

Nagaraj Sabarinathan ◽

Sharada Duddu. S

Keyword(s):

Transition Metal ◽

Visible Light ◽

Practical Approach ◽

Hypervalent Iodine ◽

Radical Mechanism ◽

Photoredox Catalysis ◽

Here we report a visible-light-promoted metal-free regioselective C3-H trifluoromehtylation reaction that proceeds via radical mechanism and which supported by control experiments. The combination of photoredox catalysis and hypervalent iodine reagent provides a practical approach for the present trifluoromethylation reaction and synthesis of a library of trifluoromethylated indazoles.

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