Methanol reactions on bimetallic Ru(0001)-based surfaces under UHV conditions

2013 ◽  
Vol 15 (5) ◽  
pp. 1460-1470 ◽  
Author(s):  
Pawel Gazdzicki ◽  
Peter Jakob
Keyword(s):  
Methanol Reactions

Methanol Reactions over Oxygen-Modified Re Surfaces:  Influence of Surface Structure and Oxidation†

2004 ◽  
Vol 108 (38) ◽  
pp. 14643-14651 ◽  
Author(s):  
Ally S. Y. Chan ◽  
Wenhua Chen ◽  
Hao Wang ◽  
John E. Rowe ◽  
Theodore E. Madey
Keyword(s):  
Surface Structure ◽  
Methanol Reactions

Statistical Mechanics of Deuterium Exchange Reactions: Recalculation of Thermodynamic Properties of Water-Methanol Reactions

1979 ◽  
Vol 32 (3) ◽  
pp. 465 ◽  
Author(s):  
JR Khurma ◽  
DV Fenby
Keyword(s):  
Liquid Phase ◽  
Thermodynamic Properties ◽  
Force Field ◽  
Gas Phase ◽  
Vapour Pressure ◽  
The Other ◽  
Exchange Reactions ◽  
Statistical Mechanical ◽  
Experimental Values ◽  
Methanol Reactions

Thermodynamic properties of the reactions CH3OH+HDO → CH3D+H2O CH3OH+D2O → CH3OD+HDO in the gas phase are calculated from statistical mechanical equations. Two sets of calculated harmonic frequencies are used: one obtained from an experimental force field and the other from an ab initio force field. Thermodynamic properties of the corresponding liquid-phase reactions are obtained by combining the gas-phase values with vapour-pressure isotope effect results. The calculated properties are compared with published experimental values.

scholarly journals The active sites of Cu–ZnO catalysts for water gas shift and CO hydrogenation reactions

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhenhua Zhang ◽  
Xuanye Chen ◽  
Jincan Kang ◽  
Zongyou Yu ◽  
Jie Tian ◽  
...  
Keyword(s):  
Active Sites ◽  
Co Hydrogenation ◽  
Water Gas Shift ◽  
Reaction Conditions ◽  
Hydrogenation Reactions ◽  
Cu Catalysts ◽  
Water Gas ◽  
Zn Alloy ◽  
Methanol Reactions

AbstractCu–ZnO–Al2O3 catalysts are used as the industrial catalysts for water gas shift (WGS) and CO hydrogenation to methanol reactions. Herein, via a comprehensive experimental and theoretical calculation study of a series of ZnO/Cu nanocrystals inverse catalysts with well-defined Cu structures, we report that the ZnO–Cu catalysts undergo Cu structure-dependent and reaction-sensitive in situ restructuring during WGS and CO hydrogenation reactions under typical reaction conditions, forming the active sites of CuCu(100)-hydroxylated ZnO ensemble and CuCu(611)Zn alloy, respectively. These results provide insights into the active sites of Cu–ZnO catalysts for the WGS and CO hydrogenation reactions and reveal the Cu structural effects, and offer the feasible guideline for optimizing the structures of Cu–ZnO–Al2O3 catalysts.

H-[B]-ZSM-5 as catalyst for methanol reactions

1995 ◽  
Vol 124 (2) ◽  
pp. 345-354 ◽  
Author(s):  
Erik Unneberg ◽  
Stein Kolboe
Keyword(s):  
Methanol Reactions

Methanol Reactions In Space

2016 ◽  
Vol 94 (6) ◽  
pp. 24-24
Keyword(s):  
Methanol Reactions

Catalyseurs de synthese de methanol: reactions competitives CO(CO2)/H2/olefines

1986 ◽  
Vol 37 (2-3) ◽  
pp. 369-375 ◽  
Author(s):  
B. Denise ◽  
R.P.A. Sneeden
Keyword(s):  
Methanol Reactions

scholarly journals Identification of the active sites of Cu-ZnO catalysts for water gas shift and CO hydrogenation reactions

2021 ◽  
Author(s):  
Zhenhua Zhang ◽  
Xuanye Chen ◽  
Jincan Kang ◽  
Zongyou Yu ◽  
Jie Tian ◽  
...  
Keyword(s):  
Theoretical Calculation ◽  
Active Sites ◽  
Co Hydrogenation ◽  
Water Gas Shift ◽  
Reaction Conditions ◽  
Hydrogenation Reactions ◽  
Water Gas ◽  
Zn Alloy ◽  
Methanol Reactions

Abstract Cu-ZnO-Al2O3 catalysts are used as the industrial catalysts for water gas shift (WGS) and CO hydrogenation to methanol reactions. Herein, via a comprehensive experimental and theoretical calculation study of a series of ZnO/Cu nanocrystals inverse catalysts with well-defined Cu structures, we report that the Cu-ZnO catalysts undergo Cu structure-dependent and reaction-sensitive in situ restructuring during WGS and CO hydrogenation reactions under typical reaction conditions, forming the active sites of CuCu(100)-hydroxylated ZnO ensemble and CuCu(611)Zn alloy, respectively. These results conclude the long-existing debates and provide the feasible guideline for optimizing the structures of Cu-ZnO-Al2O3 catalysts.

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