The X-ray crystal structure of trans-bis(sulphur dioxide)tetrakis(triphenylphosphineoxide)manganese(II) di-iodide, a compound which undergoes demi-reversible binding of sulphur dioxide: the first crystallographically characterised example of O-bonded sulphur dioxide in a transition metal complex

1984 ◽  
pp. 1283 ◽  
Author(s):  
George A. Gott ◽  
John Fawcett ◽  
Charles A. McAuliffe ◽  
David R. Russell
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Sulphur Dioxide ◽  
Transition Metal Complex ◽  
Reversible Binding ◽  
X Ray

Reversible Binding of Dioxygen by a Non-Transition-Metal Complex

2005 ◽  
Vol 117 (18) ◽  
pp. 2827-2831 ◽  
Author(s):  
Gleb A. Abakumov ◽  
Andrey I. Poddel'sky ◽  
Ekaterina V. Grunova ◽  
Vladimir K. Cherkasov ◽  
Georgy K. Fukin ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Reversible Binding

Single-crystal x-ray and neutron diffraction studies of an .eta.2-dihydrogen transition-metal complex: trans-[Fe(.eta.2-H2)(H)(PPh2CH2CH2PPh2)2]BPh4

1989 ◽  
Vol 111 (24) ◽  
pp. 8823-8827 ◽  
Author(s):  
John S. Ricci ◽  
Thomas F. Koetzle ◽  
Maria T. Bautista ◽  
Theresa M. Hofstede ◽  
Robert H. Morris ◽  
...  
Keyword(s):  
Transition Metal ◽  
Neutron Diffraction ◽  
Metal Complex ◽  
Single Crystal ◽  
Transition Metal Complex ◽  
X Ray

scholarly journals Inelastic X-ray Scattering of a Transition-Metal Complex (FeCl4–): Vibrational Spectroscopy for All Normal Modes

2013 ◽  
Vol 52 (12) ◽  
pp. 6767-6769 ◽  
Author(s):  
Weibing Dong ◽  
Hongxin Wang ◽  
Marilyn M. Olmstead ◽  
James C. Fettinger ◽  
Jay Nix ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Vibrational Spectroscopy ◽  
Transition Metal Complex ◽  
Normal Modes ◽  
X Ray ◽  
X Ray Scattering ◽  
Ray Scattering

S4N4 und seine Derivate: α-FeCl3 · S4N4, ein Übergangsmetallkomplex mit dem S4N4-Ligand / S4N4 and its Derivatives: α-FeCl3 · S4N4, a Transition Metal Complex with the S4N4 Ligand

1980 ◽  
Vol 35 (7) ◽  
pp. 855-859 ◽  
Author(s):  
Ulf Thewalt
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Iron Atom ◽  
Transition Metal Complex ◽  
Lattice Parameters ◽  
Monoclinic Space Group ◽  
Space Group ◽  
X Ray

The adduct α-FeCl3 · S4N4 has been prepared from FeCl3 and S4N4 in CCl4. The new compound crystallizes in the monoclinic space group P 21/c with Z = 4 and lattice parameters a = 6.360(2), b = 13.066(4), c = 12.686(5) Å, and β = 99.43(3)°. An X-ray analysis shows that the S4N4 ring is bonded via one of its nitrogen atoms to the iron atom of the FeCl3 group and that the four ligand atoms around the iron atom form a tetrahedron. The structure of the complex is similar to the known structure of BF3 · S4N4

Sign in / Sign up

Export Citation Format

Share Document